MiMeDB: Showing metabocard for di-mu-Sulfido-diiron(1+) (MMDBc0057111)

Record Information

Version

1.0

Status

Detected and Quantified

Creation Date

2022-10-17 17:53:18 UTC

Update Date

2022-10-17 17:53:18 UTC

Metabolite ID

MMDBc0057111

Metabolite Identification

Common Name

di-mu-Sulfido-diiron(1+)

Description

di-mu-sulfido-diiron(1+) is also known as [2fe-2S](1+). Based on a literature review very few articles have been published on di-mu-sulfido-diiron(1+).

Structure

MOL SDF PDB SMILES InChI

Synonyms

Value	Source
[2Fe-2S](1+)	ChEBI
[Fe2(mu-S)2](+)	ChEBI
[Fe2S2](+)	ChEBI
Di-mu-sulphido-diiron(1+)	Generator

Molecular Formula

Fe₂S₂

Average Mass

175.81

Monoisotopic Mass

175.813466

IUPAC Name

cyclodiferrathian-2-ylium

Traditional Name

di-mu-sulfido-diiron(1+)

CAS Registry Number

Not Available

SMILES

S1[Fe]S[Fe+]1

InChI Identifier

InChI=1S/2Fe.2S/q;+1;;

InChI Key

MAGIRAZQQVQNKP-UHFFFAOYSA-N

Chemical Taxonomy

Functional Ontology

Not Available

Physical Properties

State

Not Available

Predicted Properties

Property	Value	Source
logP	2.03	ChemAxon
Physiological Charge	1	ChemAxon
Hydrogen Acceptor Count	0	ChemAxon
Hydrogen Donor Count	0	ChemAxon
Polar Surface Area	0 Å²	ChemAxon
Rotatable Bond Count	0	ChemAxon
Refractivity	11.51 m³·mol⁻¹	ChemAxon
Polarizability	10.29 Å³	ChemAxon
Number of Rings	1	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	Yes	ChemAxon
MDDR-like Rule	No	ChemAxon

Spectra

Not Available

Biological Properties

Cellular Locations

Not Available

Biospecimen Locations

Not Available

Tissue Locations

Not Available

Associated OMIM IDs

114500 (Colorectal cancer)
610247 (Eosinophilic esophagitis)

Human Proteins and Enzymes

Protein ID	Protein Name	Protein Type	Uniprot ID	Species

Human Pathways

Pathways

Name	SMPDB/PathBank

Metabolic Reactions

Reactions

Reaction ID	Precursor	Product	Enzyme	Reaction Type	Data Source	Reference
MMDBr0024391	alpha-Ketoisovaleric acid	di-mu-Sulfido-diiron(1+)	Ketoisovalerate oxidoreductase subunit VorC	Redox reaction	RHEA	34755880
MMDBr0024406	L-Glutamic acid	alpha-Ketoglutarate	Ferredoxin-dependent glutamate synthase 1	Synthesis	RHEA	34755880
MMDBr0024421	Indolepyruvate	di-mu-Sulfido-diiron(1+)	Indolepyruvate oxidoreductase subunit IorA	Redox reaction	RHEA	34755880
MMDBr0024429	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	Pyruvate synthase subunit PorB	Redox reaction; Synthesis	RHEA	34755880
MMDBr0024430	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	Pyruvate:ferredoxin oxidoreductase	Redox reaction	RHEA	34755880
MMDBr0024431	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Pyruvate:ferredoxin oxidoreductase	Redox reaction	RHEA	34755880
MMDBr0024453	(1R,4R)-camphor	(1R,4R,5R)-5-hydroxycamphor	Camphor 5-monooxygenase	Oxygenation	RHEA	34755880
MMDBr0024499	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	Phycocyanobilin:ferredoxin oxidoreductase	Redox reaction	RHEA	34755880
MMDBr0024532	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	Tungsten-containing aldehyde ferredoxin oxidoreductase	Redox reaction	RHEA	34755880
MMDBr0024537	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Toluene 1,2-dioxygenase system ferredoxin--NAD(+) reductase component	Reduction	RHEA	34755880
MMDBr0024539	Tetra-mu3-sulfido-tetrairon(2+)	5'-Deoxyadenosine	Lipoyl synthase	Synthesis	RHEA	34755880
MMDBr0024558	alpha-Ketoglutarate	di-mu-Sulfido-diiron(1+)	2-oxoglutarate synthase subunit KorA	Redox reaction; Synthesis	RHEA	34755880
MMDBr0024566	Hydrogen	di-mu-Sulfido-diiron(1+)	Membrane-bound hydrogenase subunit alpha	Hydrogenation	RHEA	34755880
MMDBr0024588	di-mu-Sulfido-diiron(2+)	Nitrite	Assimilatory ferredoxin-dependent nitrite reductase	Reduction	RHEA	34755880
MMDBr0024639	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	Molybdenum-containing formylmethanofuran dehydrogenase 1 subunit C	Dehydrogenation	RHEA	34755880
MMDBr0024650	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Ferredoxin--NADP reductase	Dehydrogenation; Reduction	RHEA	34755880
MMDBr0024661	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Ubiquinone biosynthesis monooxygenase COQ6, mitochondrial	Oxygenation	RHEA	34755880
MMDBr0024671	Carbon monoxide	di-mu-Sulfido-diiron(1+)	Acetyl-CoA decarbonylase/synthase complex subunit alpha	Dehydrogenation; Synthesis	RHEA	34755880
MMDBr0024686	Nitrogen	Hydrogen	Nitrogenase iron protein	Nitrogen fixation	RHEA	34755880
MMDBr0024695	Nitrite	Nitrate	Assimilatory nitrate reductase	Reduction	RHEA	34755880
MMDBr0024707	di-mu-Sulfido-diiron(1+)	5'-Deoxyadenosine	Biotin synthase	Synthesis	RHEA	34755880
MMDBr0024708	di-mu-Sulfido-diiron(1+)	5'-Deoxyadenosine	Biotin synthase	Synthesis	RHEA	34755880
MMDBr0024734	Hydrogen sulfide	di-mu-Sulfido-diiron(1+)	Sulfite reductase [ferredoxin]	Reduction	RHEA	34755880
MMDBr0024767	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	Glyceraldehyde-3-phosphate:ferredoxin oxidoreductase	Redox reaction	RHEA	34755880
MMDBr0024770	di-mu-Sulfido-diiron(1+)	L-Cysteine	Probable tRNA sulfurtransferase	Sulfuration	RHEA	34755880
MMDBr0024782	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	4-hydroxy-3-methylbut-2-enyl diphosphate reductase	Reduction	RHEA	34755880
MMDBr0024783	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	20-oxo-5-O-mycaminosyltylactone 23-monooxygenase	Oxygenation	RHEA	34755880
MMDBr0024789	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	4-hydroxy-3-methylbut-2-enyl diphosphate reductase	Reduction	RHEA	34755880
MMDBr0024803	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Biflaviolin synthase CYP158A2	Synthesis	RHEA	34755880
MMDBr0024804	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Biflaviolin synthase CYP158A2	Synthesis	RHEA	34755880
MMDBr0024807	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	4-hydroxy-3-methylbut-2-en-1-yl diphosphate synthase (ferredoxin)	Synthesis	RHEA	34755880
MMDBr0024856	beta-Carotene	Zeaxanthin	Beta-carotene hydroxylase	Hydroxylation	RHEA	34755880
MMDBr0024858	di-mu-Sulfido-diiron(2+)	Copper	Photosystem I P700 chlorophyll a apoprotein A2		RHEA	34755880
MMDBr0024876	Pentalenene	di-mu-Sulfido-diiron(2+)	Pentalenene oxygenase	Oxygenation	RHEA	34755880
MMDBr0024880	Cholestenone	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Oxygenation	RHEA	34755880
MMDBr0024881	Cholestenone	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Oxygenation	RHEA	34755880
MMDBr0024888	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	3-ketosteroid-9-alpha-monooxygenase, oxygenase component	Reduction	RHEA	34755880
MMDBr0024889	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	3-ketosteroid-9-alpha-monooxygenase, oxygenase component	Oxygenation	RHEA	34755880
MMDBr0024890	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Epi-isozizaene 5-monooxygenase/(E)-beta-farnesene synthase	Synthesis	RHEA	34755880
MMDBr0024891	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Epi-isozizaene 5-monooxygenase/(E)-beta-farnesene synthase	Synthesis	RHEA	34755880
MMDBr0024901	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Spheroidene monooxygenase	Oxygenation	RHEA	34755880
MMDBr0024902	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Spheroidene monooxygenase	Oxygenation	RHEA	34755880
MMDBr0024903	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Spheroidene monooxygenase	Oxygenation	RHEA	34755880
MMDBr0024904	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Putidaredoxin reductase CamA	Reduction	RHEA	34755880
MMDBr0024930	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Pentalenolactone synthase	Synthesis	RHEA	34755880
MMDBr0024931	5-b-Cholestane-3a ,7a ,12a-triol	di-mu-Sulfido-diiron(2+)	Vitamin D(3) 25-hydroxylase	Hydroxylation	RHEA	34755880
MMDBr0024942	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Mycocyclosin synthase	Synthesis	RHEA	34755880
MMDBr0024943	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Pulcherriminic acid synthase	Synthesis	RHEA	34755880
MMDBr0024970	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	Chlorophyllide reductase subunit Z	Reduction	RHEA	34755880
MMDBr0024996	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Cytochrome P450 monooxygenase PikC	Oxygenation	RHEA	34755880
MMDBr0024997	6-deoxyerythronolide B	erythronolide B	6-deoxyerythronolide B hydroxylase	Hydroxylation	RHEA	34755880
MMDBr0025000	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Cytochrome P450 monooxygenase PikC	Oxygenation	RHEA	34755880
MMDBr0025001	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Cytochrome P450 monooxygenase PikC	Oxygenation	RHEA	34755880
MMDBr0025002	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Cytochrome P450 monooxygenase PikC	Oxygenation	RHEA	34755880
MMDBr0025003	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Cytochrome P450 monooxygenase PikC	Oxygenation	RHEA	34755880
MMDBr0025004	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Cytochrome P450 monooxygenase PikC	Oxygenation	RHEA	34755880
MMDBr0025051	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Probable NADPH:adrenodoxin oxidoreductase, mitochondrial	Redox reaction	RHEA	34755880
MMDBr0025052	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	2-oxoacid:ferredoxin oxidoreductase subunit alpha	Redox reaction	RHEA	34755880
MMDBr0025053	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	F(420)H(2) dehydrogenase subunit F	Dehydrogenation	RHEA	34755880
MMDBr0025054	di-mu-Sulfido-diiron(1+)	L-Cysteine	Ferredoxin-thioredoxin reductase, catalytic chain	Reduction	RHEA	34755880
MMDBr0025064	di-mu-Sulfido-diiron(1+)	5'-Deoxyadenosine	Ribosomal RNA large subunit methyltransferase Cfr	Methylation	RHEA	34755880
MMDBr0025095	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	2-hydroxy-5-methyl-1-naphthoate 7-hydroxylase	Hydroxylation	RHEA	34755880
MMDBr0025102	di-mu-Sulfido-diiron(1+)	5'-Deoxyadenosine	Ribosomal RNA large subunit methyltransferase N	Methylation	RHEA	34755880
MMDBr0025145	di-mu-Sulfido-diiron(1+)	5'-Deoxyadenosine	Probable dual-specificity RNA methyltransferase RlmN	Methylation	RHEA	34755880
MMDBr0025175	27-Hydroxycholesterol	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Hydroxylation; Oxygenation	RHEA	34755880
MMDBr0025176	27-Hydroxycholesterol	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Hydroxylation; Oxygenation	RHEA	34755880
MMDBr0025178	Cholestenone	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Hydroxylation; Oxygenation	RHEA	34755880
MMDBr0025179	Cholestenone	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Hydroxylation; Oxygenation	RHEA	34755880
MMDBr0025180	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Hydroxylation; Oxygenation	RHEA	34755880
MMDBr0025181	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Hydroxylation; Oxygenation	RHEA	34755880
MMDBr0025182	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Hydroxylation; Oxygenation	RHEA	34755880
MMDBr0025183	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Hydroxylation; Oxygenation	RHEA	34755880
MMDBr0025245	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Na(+)-translocating ferredoxin:NAD(+) oxidoreductase complex subunit B	Redox reaction	RHEA	34755880
MMDBr0025253	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Caffeyl-CoA reductase-Etf complex subunit CarC	Reduction	RHEA	34755880
MMDBr0025254	lactic acid	di-mu-Sulfido-diiron(2+)	Lactate dehydrogenase (NAD(+),ferredoxin) subunit LctB	Dehydrogenation	RHEA	34755880
MMDBr0025287	di-mu-Sulfido-diiron(1+)	Epothilone A	Epothilone C/D epoxidase	Oxidation	RHEA	34755880
MMDBr0025288	Epothilone D	Epothilone B	Epothilone C/D epoxidase	Oxidation	RHEA	34755880
MMDBr0025309	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	Chlorophyllide reductase subunit Z	Reduction	RHEA	34755880
MMDBr0025310	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	Chlorophyllide reductase subunit Z	Reduction	RHEA	34755880
MMDBr0025313	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	dTDP-4-dehydro-2,6-dideoxy-D-glucose 3-dehydratase	Hydration/dehydration of C-O bond	RHEA	34755880
MMDBr0025329	Cholestenone	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Hydroxylation; Oxygenation	RHEA	34755880
MMDBr0025359	Vitamin D3	Calcidiol	Vitamin D3 dihydroxylase	Hydroxylation	RHEA	34755880
MMDBr0025360	Calcidiol	Calcitriol	Vitamin D3 dihydroxylase	Hydroxylation	RHEA	34755880
MMDBr0025397	Cholestenone	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Oxygenation	RHEA	34755880
MMDBr0025398	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Hydroxylation; Oxygenation	RHEA	34755880
MMDBr0025399	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Hydroxylation; Oxygenation	RHEA	34755880
MMDBr0025400	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Hydroxylation; Oxygenation	RHEA	34755880
MMDBr0025401	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Steroid C26-monooxygenase	Hydroxylation; Oxygenation	RHEA	34755880
MMDBr0025402	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Cytochrome P450 CYP107DY1	Hydroxylation	RHEA	34755880
MMDBr0025408	butachlor	di-mu-Sulfido-diiron(2+)	Chloroacetanilide N-alkylformylase, oxygenase component	Oxygenation	RHEA	34755880
MMDBr0025409	alachlor	di-mu-Sulfido-diiron(2+)	Chloroacetanilide N-alkylformylase, oxygenase component	Oxygenation	RHEA	34755880
MMDBr0025410	Tricosanoic acid	di-mu-Sulfido-diiron(2+)	Chloroacetanilide N-alkylformylase, oxygenase component	Oxygenation	RHEA	34755880
MMDBr0025560	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	Ferredoxin:CoB-CoM heterodisulfide reductase subunit B	Reduction	RHEA	34755880
MMDBr0025576	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Ferredoxin/F(420)H(2)-dependent CoB-CoM heterodisulfide reductase subunit B	Reduction	RHEA	34755880
MMDBr0025577	di-mu-Sulfido-diiron(1+)	Hydrogen	H(2):CoB-CoM heterodisulfide,ferredoxin reductase subunit A	Reduction	RHEA	34755880
MMDBr0025578	di-mu-Sulfido-diiron(1+)	formate	H(2)/formate:CoB-CoM heterodisulfide,ferredoxin reductase subunit A	Reduction	RHEA	34755880
MMDBr0025618	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Dihydrorhizobitoxine desaturase	Desaturation	RHEA	34755880
MMDBr0025619	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Dihydrorhizobitoxine desaturase	Desaturation	RHEA	34755880
MMDBr0025637	di-mu-Sulfido-diiron(1+)	Formaldehyde	Dicamba O-demethylase, oxygenase component	Demethylation	RHEA	34755880
MMDBr0025658	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Ubiquinone biosynthesis monooxygenase COQ6, mitochondrial	Oxygenation	RHEA	34755880
MMDBr0025659	di-mu-Sulfido-diiron(1+)	di-mu-Sulfido-diiron(2+)	Ubiquinone biosynthesis monooxygenase COQ6, mitochondrial	Oxygenation	RHEA	34755880
MMDBr0025973	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	NADPH-dependent diflavin oxidoreductase 1	Redox reaction	RHEA	34755880
MMDBr0025974	di-mu-Sulfido-diiron(2+)	di-mu-Sulfido-diiron(1+)	NADPH-dependent diflavin oxidoreductase 1	Redox reaction	RHEA	34755880

Health Effects and Bioactivity

Health Outcome/Bioactivity	Metabolite Response/Effect	Evidence Type	Host and Biospecimen	Data Source	Reference

Microbial Sources

Superkingdom/Kingdom	Phylum	Total species	Hosts and Body Sites	Microbial Links

Exposure Sources

Other Exposures

Source Type	Data Source	Reference

Host Biospecimen and Location

Host and Biospecimen	Status	Mean	Std	Min	Max	Units	Age	Sex	Health Condition	Data Source	Reference

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FooDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

21865187

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

Not Available

PDB ID

Not Available

ChEBI ID

33738

Food Biomarker Ontology

Not Available

References

Synthesis Reference

Not Available

General References

Bansal P, Morgat A, Axelsen KB, Muthukrishnan V, Coudert E, Aimo L, Hyka-Nouspikel N, Gasteiger E, Kerhornou A, Neto TB, Pozzato M, Blatter MC, Ignatchenko A, Redaschi N, Bridge A: Rhea, the reaction knowledgebase in 2022. Nucleic Acids Res. 2022 Jan 7;50(D1):D693-D700. doi: 10.1093/nar/gkab1016. [PubMed:34755880 ]

Showing metabocard for di-mu-Sulfido-diiron(1+) (MMDBc0057111)

MOL for #<Metabolite:0x00007f91f12b5798>

3D MOL for #<Metabolite:0x00007f91f12b5798>

3D SDF for #<Metabolite:0x00007f91f12b5798>

3D-SDF for #<Metabolite:0x00007f91f12b5798>

PDB for #<Metabolite:0x00007f91f12b5798>

3D PDB for #<Metabolite:0x00007f91f12b5798>

SMILES for #<Metabolite:0x00007f91f12b5798>

INCHI for #<Metabolite:0x00007f91f12b5798>

Structure for #<Metabolite:0x00007f91f12b5798>

3D Structure for #<Metabolite:0x00007f91f12b5798>