MiMeDB: Showing metabocard for L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid (MMDBc0056055)

Record Information

Version

2.0

Status

Detected and Quantified

Creation Date

2022-06-17 20:14:29 UTC

Update Date

2025-10-07 16:09:32 UTC

Metabolite ID

MMDBc0056055

Metabolite Identification

Common Name

L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid

Description

L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid is a peptide compound belonging to the class of amino acids and peptides. There is limited literature available on this metabolite, indicating that further research may be necessary to fully understand its biological roles and implications.

Structure

MOL SDF PDB SMILES InChI


  Mrv1652306172222142D          

 31 30  0  0  1  0            999 V2000
   10.1490    4.0401    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3979    3.8842    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5877    4.0401    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.9379    4.5078    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.4485    5.2874    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.6384    5.4433    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.8789    4.8196    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.0476    3.4164    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    4.7481    4.3519    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    7.9886    5.9110    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    6.0983    4.8196    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.0688    4.9755    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.2375    3.5724    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.0181    3.5724    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.7186    6.6906    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   10.4190    5.4433    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    2.3177    2.6369    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    5.2882    4.9755    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    8.7987    5.7551    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    6.3683    4.0401    0.0000 O   0  5  0  0  0  0  0  0  0  0  0  0
    8.5287    4.3519    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.6974    2.9487    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.9675    4.3519    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.8283    3.4164    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.4780    2.9487    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.9084    6.8465    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    8.2587    7.3142    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    9.3388    4.1960    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.7776    4.1960    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.2080    3.7283    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
    7.1785    6.0669    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
  3  2  1  0  0  0  0
  4  2  1  0  0  0  0
  6  5  1  0  0  0  0
  7  1  1  0  0  0  0
  8  3  1  0  0  0  0
  9  4  1  0  0  0  0
 10  5  1  0  0  0  0
 11  6  1  0  0  0  0
 12  7  1  0  0  0  0
 13  8  1  0  0  0  0
 14  9  1  0  0  0  0
 15 10  1  0  0  0  0
  7 16  1  6  0  0  0
  8 17  1  1  0  0  0
  9 18  1  6  0  0  0
 18 11  2  0  0  0  0
 10 19  1  1  0  0  0
 19 12  2  0  0  0  0
 11 20  1  4  0  0  0
 12 21  1  4  0  0  0
 22 13  2  0  0  0  0
 23 13  1  0  0  0  0
 24 14  2  0  0  0  0
 25 14  1  0  0  0  0
 26 15  2  0  0  0  0
 27 15  1  0  0  0  0
  7 28  1  6  0  0  0
  8 29  1  1  0  0  0
  9 30  1  6  0  0  0
 10 31  1  1  0  0  0
M  CHG  1  20  -1
M  END


  Mrv1652306172222142D          

 31 30  0  0  1  0            999 V2000
   10.1490    4.0401    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3979    3.8842    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5877    4.0401    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.9379    4.5078    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.4485    5.2874    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.6384    5.4433    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.8789    4.8196    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.0476    3.4164    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    4.7481    4.3519    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    7.9886    5.9110    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    6.0983    4.8196    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.0688    4.9755    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.2375    3.5724    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.0181    3.5724    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.7186    6.6906    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   10.4190    5.4433    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    2.3177    2.6369    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    5.2882    4.9755    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    8.7987    5.7551    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    6.3683    4.0401    0.0000 O   0  5  0  0  0  0  0  0  0  0  0  0
    8.5287    4.3519    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.6974    2.9487    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.9675    4.3519    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.8283    3.4164    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.4780    2.9487    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.9084    6.8465    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    8.2587    7.3142    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    9.3388    4.1960    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.7776    4.1960    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.2080    3.7283    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
    7.1785    6.0669    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
  3  2  1  0  0  0  0
  4  2  1  0  0  0  0
  6  5  1  0  0  0  0
  7  1  1  0  0  0  0
  8  3  1  0  0  0  0
  9  4  1  0  0  0  0
 10  5  1  0  0  0  0
 11  6  1  0  0  0  0
 12  7  1  0  0  0  0
 13  8  1  0  0  0  0
 14  9  1  0  0  0  0
 15 10  1  0  0  0  0
  7 16  1  6  0  0  0
  8 17  1  1  0  0  0
  9 18  1  6  0  0  0
 18 11  2  0  0  0  0
 10 19  1  1  0  0  0
 19 12  2  0  0  0  0
 11 20  1  4  0  0  0
 12 21  1  4  0  0  0
 22 13  2  0  0  0  0
 23 13  1  0  0  0  0
 24 14  2  0  0  0  0
 25 14  1  0  0  0  0
 26 15  2  0  0  0  0
 27 15  1  0  0  0  0
  7 28  1  6  0  0  0
  8 29  1  1  0  0  0
  9 30  1  6  0  0  0
 10 31  1  1  0  0  0
M  CHG  1  20  -1
M  END
> <DATABASE_ID>
MMDBc0056055

> <DATABASE_NAME>
MIME

> <SMILES>
[H][C@@](C)(N)C(O)=N[C@]([H])(CCC([O-])=N[C@]([H])(CCC[C@]([H])(N)C(O)=O)C(O)=O)C(O)=O

> <INCHI_IDENTIFIER>
InChI=1S/C15H26N4O8/c1-7(16)12(21)19-10(15(26)27)5-6-11(20)18-9(14(24)25)4-2-3-8(17)13(22)23/h7-10H,2-6,16-17H2,1H3,(H,18,20)(H,19,21)(H,22,23)(H,24,25)(H,26,27)/p-1/t7-,8-,9+,10+/m0/s1

> <INCHI_KEY>
FMNCPUGORYYCEM-AXTSPUMRSA-M

> <FORMULA>
C15H25N4O8

> <MOLECULAR_WEIGHT>
389.386

> <EXACT_MASS>
389.167787361

> <JCHEM_ACCEPTOR_COUNT>
12

> <JCHEM_ATOM_COUNT>
52

> <JCHEM_AVERAGE_POLARIZABILITY>
37.65418067626577

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
6

> <JCHEM_FORMAL_CHARGE>
-1

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(4R)-N-[(1R,5S)-5-amino-1,5-dicarboxypentyl]-4-{[(2S)-2-amino-1-hydroxypropylidene]amino}-4-carboxybutanecarboximidate

> <JCHEM_LOGP>
-5.633571745676178

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
0

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-1

> <JCHEM_PKA>
3.002243170790513

> <JCHEM_PKA_STRONGEST_ACIDIC>
1.8955442579246076

> <JCHEM_PKA_STRONGEST_BASIC>
9.849698062630521

> <JCHEM_POLAR_SURFACE_AREA>
231.94999999999996

> <JCHEM_REFRACTIVITY>
100.6183

> <JCHEM_ROTATABLE_BOND_COUNT>
13

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(4R)-N-[(1R,5S)-5-amino-1,5-dicarboxypentyl]-4-{[(2S)-2-amino-1-hydroxypropylidene]amino}-4-carboxybutanecarboximidate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 17-JUN-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   17-JUN-22         0                                  
HETATM    1  C   UNK     0      18.945   7.541   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       6.343   7.250   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       4.830   7.541   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       7.351   8.415   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      13.904   9.870   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      12.392  10.161   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      18.441   8.997   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       3.822   6.377   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       8.863   8.124   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      14.912  11.034   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      11.383   8.997   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      16.928   9.288   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       2.310   6.668   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       9.367   6.668   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      14.408  12.489   0.000  0.00  0.00           C+0
HETATM   16  N   UNK     0      19.449  10.161   0.000  0.00  0.00           N+0
HETATM   17  N   UNK     0       4.326   4.922   0.000  0.00  0.00           N+0
HETATM   18  N   UNK     0       9.871   9.288   0.000  0.00  0.00           N+0
HETATM   19  N   UNK     0      16.424  10.743   0.000  0.00  0.00           N+0
HETATM   20  O   UNK     0      11.888   7.541   0.000  0.00  0.00           O-1
HETATM   21  O   UNK     0      15.920   8.124   0.000  0.00  0.00           O+0
HETATM   22  O   UNK     0       1.302   5.504   0.000  0.00  0.00           O+0
HETATM   23  O   UNK     0       1.806   8.124   0.000  0.00  0.00           O+0
HETATM   24  O   UNK     0      10.879   6.377   0.000  0.00  0.00           O+0
HETATM   25  O   UNK     0       8.359   5.504   0.000  0.00  0.00           O+0
HETATM   26  O   UNK     0      12.896  12.780   0.000  0.00  0.00           O+0
HETATM   27  O   UNK     0      15.416  13.653   0.000  0.00  0.00           O+0
HETATM   28  H   UNK     0      17.432   7.833   0.000  0.00  0.00           H+0
HETATM   29  H   UNK     0       3.318   7.833   0.000  0.00  0.00           H+0
HETATM   30  H   UNK     0       7.855   6.959   0.000  0.00  0.00           H+0
HETATM   31  H   UNK     0      13.400  11.325   0.000  0.00  0.00           H+0
CONECT    1    7                                                            
CONECT    2    3    4                                                       
CONECT    3    2    8                                                       
CONECT    4    2    9                                                       
CONECT    5    6   10                                                       
CONECT    6    5   11                                                       
CONECT    7    1   12   16   28                                             
CONECT    8    3   13   17   29                                             
CONECT    9    4   14   18   30                                             
CONECT   10    5   15   19   31                                             
CONECT   11    6   18   20                                                  
CONECT   12    7   19   21                                                  
CONECT   13    8   22   23                                                  
CONECT   14    9   24   25                                                  
CONECT   15   10   26   27                                                  
CONECT   16    7                                                            
CONECT   17    8                                                            
CONECT   18    9   11                                                       
CONECT   19   10   12                                                       
CONECT   20   11                                                            
CONECT   21   12                                                            
CONECT   22   13                                                            
CONECT   23   13                                                            
CONECT   24   14                                                            
CONECT   25   14                                                            
CONECT   26   15                                                            
CONECT   27   15                                                            
CONECT   28    7                                                            
CONECT   29    8                                                            
CONECT   30    9                                                            
CONECT   31   10                                                            
MASTER        0    0    0    0    0    0    0    0   31    0   60    0
END

Synonyms

Value	Source
L-Ala-gamma-D-glu-meso-dap(1-)	ChEBI
L-Alanyl-D-glutamyl-diaminopimelate anion	ChEBI
L-Alanyl-gamma-D-glutamyl-diaminopimelate	ChEBI
L-Alanyl-gamma-D-glutamyl-meso-diaminoheptanedioate	ChEBI
L-Alanyl-gamma-D-glutamyl-meso-diaminopimelate	ChEBI
L-Alanyl-gamma-D-glutamyl-meso-diaminopimelate anion	ChEBI
L-Ala-g-D-glu-meso-dap(1-)	Generator
L-Ala-γ-D-glu-meso-dap(1-)	Generator
L-Alanyl-D-glutamyl-diaminopimelic acid anion	Generator
L-Alanyl-g-D-glutamyl-diaminopimelate	Generator
L-Alanyl-g-D-glutamyl-diaminopimelic acid	Generator
L-Alanyl-gamma-D-glutamyl-diaminopimelic acid	Generator
L-Alanyl-γ-D-glutamyl-diaminopimelate	Generator
L-Alanyl-γ-D-glutamyl-diaminopimelic acid	Generator
L-Alanyl-g-D-glutamyl-meso-diaminoheptanedioate	Generator
L-Alanyl-g-D-glutamyl-meso-diaminoheptanedioic acid	Generator
L-Alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid	Generator
L-Alanyl-γ-D-glutamyl-meso-diaminoheptanedioate	Generator
L-Alanyl-γ-D-glutamyl-meso-diaminoheptanedioic acid	Generator
L-Alanyl-g-D-glutamyl-meso-diaminopimelate	Generator
L-Alanyl-g-D-glutamyl-meso-diaminopimelic acid	Generator
L-Alanyl-gamma-D-glutamyl-meso-diaminopimelic acid	Generator
L-Alanyl-γ-D-glutamyl-meso-diaminopimelate	Generator
L-Alanyl-γ-D-glutamyl-meso-diaminopimelic acid	Generator
L-Alanyl-g-D-glutamyl-meso-diaminopimelate anion	Generator
L-Alanyl-g-D-glutamyl-meso-diaminopimelic acid anion	Generator
L-Alanyl-gamma-D-glutamyl-meso-diaminopimelic acid anion	Generator
L-Alanyl-γ-D-glutamyl-meso-diaminopimelate anion	Generator
L-Alanyl-γ-D-glutamyl-meso-diaminopimelic acid anion	Generator
L-Alanyl-g-D-glutamyl-meso-diaminopimelate(1-)	Generator
L-Alanyl-g-D-glutamyl-meso-diaminopimelic acid(1-)	Generator
L-Alanyl-gamma-D-glutamyl-meso-diaminopimelic acid(1-)	Generator
L-Alanyl-γ-D-glutamyl-meso-diaminopimelate(1-)	Generator
L-Alanyl-γ-D-glutamyl-meso-diaminopimelic acid(1-)	Generator

Molecular Formula

C₁₅H₂₅N₄O₈

Average Mass

389.386

Monoisotopic Mass

389.167787361

IUPAC Name

(4R)-N-[(1R,5S)-5-amino-1,5-dicarboxypentyl]-4-{[(2S)-2-amino-1-hydroxypropylidene]amino}-4-carboxybutanecarboximidate

Traditional Name

(4R)-N-[(1R,5S)-5-amino-1,5-dicarboxypentyl]-4-{[(2S)-2-amino-1-hydroxypropylidene]amino}-4-carboxybutanecarboximidate

CAS Registry Number

Not Available

SMILES

[H][C@@](C)(N)C(O)=N[C@]([H])(CCC([O-])=N[C@]([H])(CCC[C@]([H])(N)C(O)=O)C(O)=O)C(O)=O

InChI Identifier

InChI=1S/C15H26N4O8/c1-7(16)12(21)19-10(15(26)27)5-6-11(20)18-9(14(24)25)4-2-3-8(17)13(22)23/h7-10H,2-6,16-17H2,1H3,(H,18,20)(H,19,21)(H,22,23)(H,24,25)(H,26,27)/p-1/t7-,8-,9+,10+/m0/s1

InChI Key

FMNCPUGORYYCEM-AXTSPUMRSA-M

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as dipeptides. These are organic compounds containing a sequence of exactly two alpha-amino acids joined by a peptide bond.

Kingdom

Organic compounds

Super Class

Organic acids and derivatives

Class

Carboxylic acids and derivatives

Sub Class

Amino acids, peptides, and analogues

Direct Parent

Dipeptides

Alternative Parents

Substituents

Alpha-dipeptide
Gamma-glutamyl alpha-amino acid
Glutamine or derivatives
N-acyl-alpha-amino acid
N-acyl-alpha amino acid or derivatives
Alpha-amino acid amide
Alanine or derivatives
Alpha-amino acid
Alpha-amino acid or derivatives
L-alpha-amino acid
Tricarboxylic acid or derivatives
N-acyl-amine
Fatty acyl
Fatty amide
Amino acid or derivatives
Secondary carboxylic acid amide
Carboxylic acid salt
Carboxamide group
Amino acid
Carboxylic acid
Organic nitrogen compound
Organic oxygen compound
Organonitrogen compound
Primary aliphatic amine
Organooxygen compound
Primary amine
Organic salt
Hydrocarbon derivative
Carbonyl group
Organic oxide
Amine
Organopnictogen compound
Organic anion
Aliphatic acyclic compound

Molecular Framework

Aliphatic acyclic compounds

External Descriptors

peptide anion (CHEBI:61401 )

Functional Ontology

Not Available

Physical Properties

State

Expected Solid

Predicted Properties

Property	Value	Source
logP	-5.6	ChemAxon
pKa (Strongest Acidic)	1.9	ChemAxon
pKa (Strongest Basic)	9.85	ChemAxon
Physiological Charge	-1	ChemAxon
Hydrogen Acceptor Count	12	ChemAxon
Hydrogen Donor Count	6	ChemAxon
Polar Surface Area	231.95 Å²	ChemAxon
Rotatable Bond Count	13	ChemAxon
Refractivity	100.62 m³·mol⁻¹	ChemAxon
Polarizability	37.65 Å³	ChemAxon
Number of Rings	0	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

Spectra

Not Available

Chromatographic Retention Times and Retention Indices

Retention Times

Chromatography Type	Technique	Column	Deposition Date	Retention Time (s)
Liquid Chromatography	HILIC	Waters Acquity UPLC-BEH Amide column (eluted)	2025-10-24	640.1
Liquid Chromatography	HILIC	Accucore 150 Amide HILIC (eluted)	2025-10-24	449.0
Liquid Chromatography	Reversed-phase	Hypersil Gold 1.9 µm C18 (eluted)	2025-10-24	68.0
Liquid Chromatography	Reversed-phase	Agilent Zorbax Eclipse Plus C18 (2.1 mm x 150 mm, 3.5 um) (eluted)	2025-10-24	279.0
Liquid Chromatography	Reversed-phase	XBridge C18 3.5u 2.1x50 mm (eluted)	2025-10-24	324.7
Liquid Chromatography	Reversed-phase	Ascentis Express C18 (eluted)	2025-10-24	226.3
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-24	416.7
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-24	1014.2
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC (retained)	2025-10-24	659.6
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-24	152.4
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-24	622.4
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-24	166.5
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-24	49.0
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (retained)	2025-10-24	579.8
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-24	695.5
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-24	61.0
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-24	295.7
Liquid Chromatography	Reversed-phase	Kinetex Core-Shell C18 2.6 um, 3.0 x 100 mm, Phenomenex (eluted)	2025-10-24	801.3
Liquid Chromatography	Reversed-phase	Waters Atlantis T3 (2.1 x 150 mm, 5 um) (eluted)	2025-10-24	581.2

Retention Indices

Chromatography Type	Peak Label	SMILES	Stationary Phase	Deposition Date	Retention Index
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_1	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	2030.25
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_2	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O	standard non polar	2025-10-24	2330.38
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_3	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	2206.12
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_4	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	2460.94
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_5	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O	standard non polar	2025-10-24	2135.21
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_6	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O	standard non polar	2025-10-24	2232.84
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_7	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	3191.46
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_8	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	2065.1
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_9	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2538.52
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_10	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	1131.88
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_11	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	1578.82
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_12	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	1344.24
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_13	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	1188.6
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_14	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O	standard non polar	2025-10-24	2442.55
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_15	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O	standard non polar	2025-10-24	1652.07
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_16	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	2923.1
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_17	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	1279.29
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_18	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	1559.47
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_19	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	2764.59
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_20	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	870.607
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_21	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O	standard non polar	2025-10-24	1871.65
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_22	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2017.78
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_23	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O	standard non polar	2025-10-24	2109.71
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_24	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	1398.85
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_25	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	1353.37
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_26	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	413.862
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_27	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	1449.11
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_28	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	799.83
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_29	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	1737.06
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_30	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	2899.75
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_31	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2622.13
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_32	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	1474.94
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_33	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	2005.96
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_34	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1621.47
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_35	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	1428.1
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_36	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	3035.88
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_37	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	1860.86
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_38	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	1457.45
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_39	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	1748.65
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_40	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	2010.01
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_41	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O	standard non polar	2025-10-24	1045.74
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_42	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1976.57
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_43	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O	standard non polar	2025-10-24	1893.77
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_44	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	1863.59
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_45	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	2015.44
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_46	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	1053.74
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_47	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	510.66
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_48	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	2304.65
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_49	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	2715.66
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_50	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1798.8
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_51	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	638.126
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_52	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1246.57
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_53	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O	standard non polar	2025-10-24	2420.98
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_54	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2695.42
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_55	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	3195.92
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_56	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	1467.22
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_57	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2487.83
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_58	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	1196.85
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_59	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	1318.0
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_60	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2435.73
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_61	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	1608.5
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_62	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	1531.38
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_63	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	1729.0
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_64	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	1839.64
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_65	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2685.33
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_66	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	1885.48
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_67	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2213.11
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_68	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2441.31
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_69	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	1941.8
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_70	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1506.03
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_71	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	2156.58
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_72	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	2078.37
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_73	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	1464.03
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_74	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	1700.31
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_75	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	660.185
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_76	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	2910.59
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_77	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	720.187
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_78	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2493.47
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_79	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	1046.31
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_80	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1563.57
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_81	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O	standard non polar	2025-10-24	2296.16
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_82	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	2020.21
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_83	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2345.43
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_84	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	2704.73
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_85	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1925.31
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_86	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	1872.41
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_87	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2368.0
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_88	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	1920.81
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_89	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1719.32
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_90	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	1921.17
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_91	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2446.71
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_92	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	3160.96
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_93	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2259.63
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_94	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	700.532
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_95	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	1313.83
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_96	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1516.18
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_97	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2726.45
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_98	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	915.271
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_99	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	2686.4
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_100	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2229.86
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_101	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1853.29
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_102	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2812.27
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_103	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1254.12
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_104	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	2742.06
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_105	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1695.94
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_106	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2483.56
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_107	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1570.93
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_108	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	3133.07
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_109	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1386.67
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_110	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	1361.94
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_111	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2022.2
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_112	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	2182.3
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_113	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1463.71
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_114	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	1517.19
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_115	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2112.99
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_116	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1498.11
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_117	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	1920.02
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_118	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1952.49
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_119	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1299.74
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_120	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2166.79
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_121	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2164.33
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_122	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	1418.68
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_123	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1485.71
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_124	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	2111.42
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_125	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1695.63
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_126	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2810.41
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_127	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	3357.58
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_128	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2759.56
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_129	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2869.94
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_130	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1859.65
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_131	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2928.4
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_132	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1634.98
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_133	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	2059.54
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_134	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1233.83
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_135	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2580.03
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_136	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1654.55
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_137	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1142.1
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_138	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	1646.92
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_139	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	-71.8048
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_140	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1782.33
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_141	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	190.418
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_142	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1777.26
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_1	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2117.49
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_2	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O	standard polar	2025-10-24	2286.53
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_3	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	1461.91
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_4	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	1354.48
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_5	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O	standard polar	2025-10-24	3488.5
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_6	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O	standard polar	2025-10-24	2169.59
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_7	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2696.87
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_8	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2926.13
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_9	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	1869.25
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_10	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2768.34
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_11	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2436.97
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_12	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	2363.09
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_13	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	1499.34
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_14	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O	standard polar	2025-10-24	2002.26
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_15	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O	standard polar	2025-10-24	1561.63
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_16	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	2582.49
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_17	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	1268.71
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_18	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	2122.8
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_19	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	2125.85
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_20	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	1955.2
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_21	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O	standard polar	2025-10-24	2247.82
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_22	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2551.95
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_23	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O	standard polar	2025-10-24	1975.82
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_24	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2661.28
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_25	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	2818.01
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_26	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2601.74
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_27	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	1284.58
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_28	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	2022.66
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_29	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	1393.98
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_30	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2182.61
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_31	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	2622.73
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_32	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	1959.34
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_33	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	1721.19
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_34	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	3553.49
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_35	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	1485.0
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_36	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	2337.63
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_37	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	2016.2
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_38	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	1935.57
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_39	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	3054.35
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_40	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	1466.33
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_41	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O	standard polar	2025-10-24	1367.75
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_42	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2141.54
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_43	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O	standard polar	2025-10-24	2023.17
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_44	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	1929.36
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_45	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	1706.71
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_46	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	1255.06
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_47	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1534.09
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_48	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	2278.77
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_49	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	2480.03
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_50	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2450.8
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_51	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	1766.46
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_52	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2896.37
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_53	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O	standard polar	2025-10-24	2099.88
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_54	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	1286.5
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_55	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2507.78
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_56	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	1290.74
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_57	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	2074.91
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_58	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	1706.62
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_59	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	1956.96
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_60	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2503.56
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_61	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	528.793
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_62	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	1705.15
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_63	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	2206.9
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_64	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	1531.74
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_65	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2594.43
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_66	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2525.76
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_67	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	3479.43
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_68	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2009.34
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_69	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	2135.62
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_70	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1836.78
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_71	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	1802.36
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_72	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	1392.86
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_73	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	2756.8
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_74	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	2812.28
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_75	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2133.01
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_76	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	1642.33
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_77	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	2595.38
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_78	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2542.89
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_79	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	2348.75
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_80	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2177.31
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_81	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O	standard polar	2025-10-24	1840.39
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_82	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	2078.99
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_83	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1603.35
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_84	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	1748.15
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_85	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1795.25
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_86	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	2977.64
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_87	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2169.13
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_88	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	2222.29
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_89	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2160.32
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_90	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	1138.1
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_91	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	1730.32
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_92	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2660.32
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_93	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2825.13
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_94	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2662.89
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_95	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	1944.07
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_96	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2104.36
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_97	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	2297.57
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_98	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1227.65
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_99	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2547.14
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_100	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	2123.56
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_101	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1422.08
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_102	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	2917.09
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_103	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2463.26
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_104	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2100.2
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_105	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1434.97
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_106	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	2915.29
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_107	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2886.67
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_108	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	2334.85
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_109	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2556.81
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_110	C[C@H](N)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	3388.72
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_111	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	844.948
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_112	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	3745.91
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_113	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2819.8
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_114	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	757.374
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_115	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1118.21
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_116	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	3087.2
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_117	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	1541.46
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_118	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2167.1
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_119	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1583.95
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_120	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	670.848
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_121	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2100.36
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_122	C[C@H](N)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	2964.68
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_123	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	134.362
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_124	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	2094.14
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_125	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2920.82
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_126	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	1284.4
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_127	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2412.32
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_128	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2100.76
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_129	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	983.909
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_130	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1476.51
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_131	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2888.49
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_132	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1779.23
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_133	C[C@H](N[Si](C)(C)C)C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	702.954
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_134	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2835.29
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_135	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	2218.9
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_136	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	3292.02
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_137	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1597.93
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_138	C[C@H](N[Si](C)(C)C)C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	1450.9
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_139	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1868.8
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_140	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1983.01
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_141	C[C@@H](C(=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	3016.66
Gas Chromatography	L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid_TMS_142	C[C@@H](C(O)=N[C@H](CCC([O-])=N[C@H](CCC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1410.7

Biological Properties

Cellular Locations

Not Available

Biospecimen Locations

Not Available

Tissue Locations

Not Available

Associated OMIM IDs

114500 (Colorectal cancer)
610247 (Eosinophilic esophagitis)

Human Proteins and Enzymes

Protein ID	Protein Name	Protein Type	Uniprot ID	Species

Human Pathways

Pathways

Name	SMPDB/PathBank

Microbial Pathways

Pathways

Not Available

Metabolic Reactions

Reactions

This table shows at most 20 reactions. For the full list of associated reactions:

See All Associated Reactions

Reaction ID	Precursor	Product	Enzyme	Reaction Type	Data Source	Reference

Health Effects and Bioactivity

Health Outcome/Bioactivity	Metabolite Response/Effect	Evidence Type	Host and Biospecimen	Data Source	Reference

Microbial Sources

Superkingdom/Kingdom	Phylum	Total species	Hosts and Body Sites	Microbial Links
Bacteria	Proteobacteria	3	Human
Bacteria/Eubacteria	Proteobacteria	1	Human

Exposure Sources

Other Exposures

Source Type	Data Source	Reference

Host Biospecimen and Location

Host and Biospecimen	Status	Mean	Std	Min	Max	Units	Age	Sex	Health Condition	Data Source	Reference

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FooDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

26332218

KEGG Compound ID

Not Available

BioCyc ID

L-ALA-GAMMA-D-GLU-DAP

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

50909834

PDB ID

Not Available

ChEBI ID

61401

Food Biomarker Ontology

Not Available

CMMC Knowledgebase

Not Available

General References

Bansal P, Morgat A, Axelsen KB, Muthukrishnan V, Coudert E, Aimo L, Hyka-Nouspikel N, Gasteiger E, Kerhornou A, Neto TB, Pozzato M, Blatter MC, Ignatchenko A, Redaschi N, Bridge A: Rhea, the reaction knowledgebase in 2022. Nucleic Acids Res. 2022 Jan 7;50(D1):D693-D700. doi: 10.1093/nar/gkab1016. [PubMed:34755880 ]

Showing metabocard for L-alanyl-gamma-D-glutamyl-meso-diaminoheptanedioic acid (MMDBc0056055)

MOL for #<Metabolite:0x00007f9ad0611be8>

3D MOL for #<Metabolite:0x00007f9ad0611be8>

3D SDF for #<Metabolite:0x00007f9ad0611be8>

3D-SDF for #<Metabolite:0x00007f9ad0611be8>

PDB for #<Metabolite:0x00007f9ad0611be8>

3D PDB for #<Metabolite:0x00007f9ad0611be8>

SMILES for #<Metabolite:0x00007f9ad0611be8>

INCHI for #<Metabolite:0x00007f9ad0611be8>

Structure for #<Metabolite:0x00007f9ad0611be8>

3D Structure for #<Metabolite:0x00007f9ad0611be8>