MiMeDB: Showing metabocard for 5-Methyltetrahydropteroyltri-L-glutamic acid (MMDBc0029547)

Record Information

Version

1.0

Status

Detected and Quantified

Creation Date

2021-11-17 23:31:49 UTC

Update Date

2022-08-31 13:43:06 UTC

Metabolite ID

MMDBc0029547

Metabolite Identification

Common Name

5-Methyltetrahydropteroyltri-L-glutamic acid

Description

5-methyltetrahydropteroyltri-L-glutamic acid is a member of the chemical class known as Biopterins and Derivatives. These are coenzymes containing a 2-amino-pteridine-4-one derivative.5-Methyltetrahydropteroyltri-L-glutamate is formed under reaction between carbonyl group of 5-methyltetrahydropteroate and amine group on one end of three replicates of glutamate. It is involved in several pathways such as tetrahydrofolate biosynthesis and methionine biosynthesis. (YMDB00518)

Structure

MOL SDF PDB SMILES InChI


  Mrv0541 08131208452D          

 50 51  0  0  0  0            999 V2000
   -2.8579   -9.0750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0000   -9.9000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5724   -6.1875    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0000   -6.6000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8579  -11.5500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5724   -5.3625    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -6.1875    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5724  -11.1375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1434  -10.3125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1434   -8.6625    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8579   -6.6000    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.0000   -7.4250    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.1434  -11.1375    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.4289   -9.9000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.2868   -4.9500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -5.3625    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.2868  -11.5500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145  -11.1375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289   -9.0750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289  -11.5500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0000  -11.5500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8579   -7.4250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -7.8375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289  -11.5500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145  -12.7875    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1434   -6.1875    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -7.8375    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434  -10.3125    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145  -13.6125    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1434  -11.1375    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289  -12.3750    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0000  -12.3750    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145  -10.3125    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   -4.2868   -4.1250    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -5.0013   -5.3625    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0000   -4.9500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289   -4.9500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.0013  -11.1375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.2868  -12.3750    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5724   -7.8375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289   -7.4250    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289  -12.3750    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1434   -7.8375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -8.6625    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145  -11.1375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8612   -9.4377    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5724   -7.0125    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -7.0125    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434  -11.9625    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9592   -9.7070    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
  6  3  1  0  0  0  0
  7  4  1  0  0  0  0
  8  5  1  0  0  0  0
 10  1  1  0  0  0  0
 11  3  1  0  0  0  0
 12  4  1  0  0  0  0
 13  5  1  0  0  0  0
 14  9  2  0  0  0  0
 15  6  1  0  0  0  0
 16  7  1  0  0  0  0
 17  8  1  0  0  0  0
 19 10  1  0  0  0  0
 19 14  1  0  0  0  0
 20 18  2  0  0  0  0
 21 18  1  0  0  0  0
 22 11  1  0  0  0  0
 23 12  1  0  0  0  0
 24 13  1  0  0  0  0
 11 26  1  1  0  0  0
 12 27  1  1  0  0  0
 13 28  1  6  0  0  0
 29 25  2  0  0  0  0
 30  9  1  0  0  0  0
 30 20  1  0  0  0  0
 31 20  1  0  0  0  0
 31 25  1  0  0  0  0
 32 21  2  0  0  0  0
 32 25  1  0  0  0  0
 33  2  1  0  0  0  0
 33 14  1  0  0  0  0
 33 18  1  0  0  0  0
 34 15  2  0  0  0  0
 35 15  1  0  0  0  0
 36 16  2  0  0  0  0
 37 16  1  0  0  0  0
 38 17  2  0  0  0  0
 39 17  1  0  0  0  0
 40 22  2  0  0  0  0
 41 23  2  0  0  0  0
 42 24  2  0  0  0  0
 43 10  1  0  0  0  0
 43 22  1  0  0  0  0
 44 19  1  0  0  0  0
 44 23  1  0  0  0  0
 45 21  1  0  0  0  0
 45 24  1  0  0  0  0
 46 10  1  0  0  0  0
 11 47  1  1  0  0  0
 12 48  1  1  0  0  0
 13 49  1  6  0  0  0
 50 19  1  0  0  0  0
M  END


  Mrv0541 08131208452D          

 50 51  0  0  0  0            999 V2000
   -2.8579   -9.0750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0000   -9.9000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5724   -6.1875    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0000   -6.6000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8579  -11.5500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5724   -5.3625    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -6.1875    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5724  -11.1375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1434  -10.3125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1434   -8.6625    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8579   -6.6000    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.0000   -7.4250    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.1434  -11.1375    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.4289   -9.9000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.2868   -4.9500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -5.3625    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.2868  -11.5500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145  -11.1375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289   -9.0750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289  -11.5500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0000  -11.5500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8579   -7.4250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -7.8375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289  -11.5500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145  -12.7875    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1434   -6.1875    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -7.8375    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434  -10.3125    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145  -13.6125    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1434  -11.1375    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289  -12.3750    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0000  -12.3750    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145  -10.3125    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   -4.2868   -4.1250    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -5.0013   -5.3625    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0000   -4.9500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289   -4.9500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.0013  -11.1375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.2868  -12.3750    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5724   -7.8375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289   -7.4250    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289  -12.3750    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1434   -7.8375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -8.6625    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145  -11.1375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8612   -9.4377    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5724   -7.0125    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -7.0125    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434  -11.9625    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9592   -9.7070    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
  6  3  1  0  0  0  0
  7  4  1  0  0  0  0
  8  5  1  0  0  0  0
 10  1  1  0  0  0  0
 11  3  1  0  0  0  0
 12  4  1  0  0  0  0
 13  5  1  0  0  0  0
 14  9  2  0  0  0  0
 15  6  1  0  0  0  0
 16  7  1  0  0  0  0
 17  8  1  0  0  0  0
 19 10  1  0  0  0  0
 19 14  1  0  0  0  0
 20 18  2  0  0  0  0
 21 18  1  0  0  0  0
 22 11  1  0  0  0  0
 23 12  1  0  0  0  0
 24 13  1  0  0  0  0
 11 26  1  1  0  0  0
 12 27  1  1  0  0  0
 13 28  1  6  0  0  0
 29 25  2  0  0  0  0
 30  9  1  0  0  0  0
 30 20  1  0  0  0  0
 31 20  1  0  0  0  0
 31 25  1  0  0  0  0
 32 21  2  0  0  0  0
 32 25  1  0  0  0  0
 33  2  1  0  0  0  0
 33 14  1  0  0  0  0
 33 18  1  0  0  0  0
 34 15  2  0  0  0  0
 35 15  1  0  0  0  0
 36 16  2  0  0  0  0
 37 16  1  0  0  0  0
 38 17  2  0  0  0  0
 39 17  1  0  0  0  0
 40 22  2  0  0  0  0
 41 23  2  0  0  0  0
 42 24  2  0  0  0  0
 43 10  1  0  0  0  0
 43 22  1  0  0  0  0
 44 19  1  0  0  0  0
 44 23  1  0  0  0  0
 45 21  1  0  0  0  0
 45 24  1  0  0  0  0
 46 10  1  0  0  0  0
 11 47  1  1  0  0  0
 12 48  1  1  0  0  0
 13 49  1  6  0  0  0
 50 19  1  0  0  0  0
M  END
> <DATABASE_ID>
MMDBc0029547

> <DATABASE_NAME>
MIME

> <SMILES>
[H][C@](N)(CCC(O)=O)C(=O)OC1=NC(=N)NC2=C1N(C)C(=CN2)C([H])(OC(=O)[C@@]([H])(N)CCC(O)=O)C([H])(C)OC(=O)[C@@]([H])(N)CCC(O)=O

> <INCHI_IDENTIFIER>
InChI=1S/C25H36N8O12/c1-10(43-22(40)11(26)3-6-15(34)35)19(44-23(41)12(27)4-7-16(36)37)14-9-30-20-18(33(14)2)21(32-25(29)31-20)45-24(42)13(28)5-8-17(38)39/h9-13,19H,3-8,26-28H2,1-2H3,(H,34,35)(H,36,37)(H,38,39)(H3,29,30,31,32)/t10?,11-,12-,13-,19?/m0/s1

> <INCHI_KEY>
SRBIKUAVFZRKSG-SUWBZHBXSA-N

> <FORMULA>
C25H36N8O12

> <MOLECULAR_WEIGHT>
640.5997

> <EXACT_MASS>
640.245268656

> <JCHEM_ACCEPTOR_COUNT>
17

> <JCHEM_AVERAGE_POLARIZABILITY>
61.434786566764004

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
9

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(4S)-4-amino-5-[(1-{[(2S)-2-amino-4-carboxybutanoyl]oxy}-1-(4-{[(2S)-2-amino-4-carboxybutanoyl]oxy}-2-imino-5-methyl-1,2,5,8-tetrahydropteridin-6-yl)propan-2-yl)oxy]-5-oxopentanoic acid

> <ALOGPS_LOGP>
-3.52

> <JCHEM_LOGP>
-9.86866000679397

> <ALOGPS_LOGS>
-3.67

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
2

> <JCHEM_PHYSIOLOGICAL_CHARGE>
1

> <JCHEM_PKA>
3.072468801782252

> <JCHEM_PKA_STRONGEST_ACIDIC>
2.333246664005935

> <JCHEM_PKA_STRONGEST_BASIC>
8.482371445044894

> <JCHEM_POLAR_SURFACE_AREA>
332.37

> <JCHEM_REFRACTIVITY>
168.90700000000007

> <JCHEM_ROTATABLE_BOND_COUNT>
20

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
1.36e-01 g/l

> <JCHEM_TRADITIONAL_IUPAC>
(4S)-4-amino-5-[(1-{[(2S)-2-amino-4-carboxybutanoyl]oxy}-1-(4-{[(2S)-2-amino-4-carboxybutanoyl]oxy}-2-imino-5-methyl-1,8-dihydropteridin-6-yl)propan-2-yl)oxy]-5-oxopentanoic acid

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 13-AUG-12   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   13-AUG-12         0                                  
HETATM    1  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   26  N   UNK     0       0.000   0.000   0.000  0.00  0.00           N+0
HETATM   27  N   UNK     0       0.000   0.000   0.000  0.00  0.00           N+0
HETATM   28  N   UNK     0       0.000   0.000   0.000  0.00  0.00           N+0
HETATM   29  N   UNK     0       0.000   0.000   0.000  0.00  0.00           N+0
HETATM   30  N   UNK     0       0.000   0.000   0.000  0.00  0.00           N+0
HETATM   31  N   UNK     0       0.000   0.000   0.000  0.00  0.00           N+0
HETATM   32  N   UNK     0       0.000   0.000   0.000  0.00  0.00           N+0
HETATM   33  N   UNK     0       0.000   0.000   0.000  0.00  0.00           N+0
HETATM   34  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   35  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   36  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   37  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   38  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   39  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   40  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   41  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   42  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   43  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   44  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   45  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   46  H   UNK     0       0.000   0.000   0.000  0.00  0.00           H+0
HETATM   47  H   UNK     0       0.000   0.000   0.000  0.00  0.00           H+0
HETATM   48  H   UNK     0       0.000   0.000   0.000  0.00  0.00           H+0
HETATM   49  H   UNK     0       0.000   0.000   0.000  0.00  0.00           H+0
HETATM   50  H   UNK     0       0.000   0.000   0.000  0.00  0.00           H+0
CONECT    1   10                                                            
CONECT    2   33                                                            
CONECT    3    6   11                                                       
CONECT    4    7   12                                                       
CONECT    5    8   13                                                       
CONECT    6    3   15                                                       
CONECT    7    4   16                                                       
CONECT    8    5   17                                                       
CONECT    9   14   30                                                       
CONECT   10    1   19   43   46                                             
CONECT   11    3   22   26   47                                             
CONECT   12    4   23   27   48                                             
CONECT   13    5   24   28   49                                             
CONECT   14    9   19   33                                                  
CONECT   15    6   34   35                                                  
CONECT   16    7   36   37                                                  
CONECT   17    8   38   39                                                  
CONECT   18   20   21   33                                                  
CONECT   19   10   14   44   50                                             
CONECT   20   18   30   31                                                  
CONECT   21   18   32   45                                                  
CONECT   22   11   40   43                                                  
CONECT   23   12   41   44                                                  
CONECT   24   13   42   45                                                  
CONECT   25   29   31   32                                                  
CONECT   26   11                                                            
CONECT   27   12                                                            
CONECT   28   13                                                            
CONECT   29   25                                                            
CONECT   30    9   20                                                       
CONECT   31   20   25                                                       
CONECT   32   21   25                                                       
CONECT   33    2   14   18                                                  
CONECT   34   15                                                            
CONECT   35   15                                                            
CONECT   36   16                                                            
CONECT   37   16                                                            
CONECT   38   17                                                            
CONECT   39   17                                                            
CONECT   40   22                                                            
CONECT   41   23                                                            
CONECT   42   24                                                            
CONECT   43   10   22                                                       
CONECT   44   19   23                                                       
CONECT   45   21   24                                                       
CONECT   46   10                                                            
CONECT   47   11                                                            
CONECT   48   12                                                            
CONECT   49   13                                                            
CONECT   50   19                                                            
MASTER        0    0    0    0    0    0    0    0   50    0  102    0
END

Synonyms

Value	Source
5-Methyltetrahydropteroyltri-L-glutamate	Generator

Molecular Formula

C₂₅H₃₆N₈O₁₂

Average Mass

640.5997

Monoisotopic Mass

640.245268656

IUPAC Name

(4S)-4-amino-5-[(1-{[(2S)-2-amino-4-carboxybutanoyl]oxy}-1-(4-{[(2S)-2-amino-4-carboxybutanoyl]oxy}-2-imino-5-methyl-1,2,5,8-tetrahydropteridin-6-yl)propan-2-yl)oxy]-5-oxopentanoic acid

Traditional Name

(4S)-4-amino-5-[(1-{[(2S)-2-amino-4-carboxybutanoyl]oxy}-1-(4-{[(2S)-2-amino-4-carboxybutanoyl]oxy}-2-imino-5-methyl-1,8-dihydropteridin-6-yl)propan-2-yl)oxy]-5-oxopentanoic acid

CAS Registry Number

Not Available

SMILES

[H][C@](N)(CCC(O)=O)C(=O)OC1=NC(=N)NC2=C1N(C)C(=CN2)C([H])(OC(=O)[C@@]([H])(N)CCC(O)=O)C([H])(C)OC(=O)[C@@]([H])(N)CCC(O)=O

InChI Identifier

InChI=1S/C25H36N8O12/c1-10(43-22(40)11(26)3-6-15(34)35)19(44-23(41)12(27)4-7-16(36)37)14-9-30-20-18(33(14)2)21(32-25(29)31-20)45-24(42)13(28)5-8-17(38)39/h9-13,19H,3-8,26-28H2,1-2H3,(H,34,35)(H,36,37)(H,38,39)(H3,29,30,31,32)/t10?,11-,12-,13-,19?/m0/s1

InChI Key

SRBIKUAVFZRKSG-SUWBZHBXSA-N

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as hexacarboxylic acids and derivatives. These are carboxylic acids containing exactly six carboxyl groups.

Kingdom

Organic compounds

Super Class

Organic acids and derivatives

Class

Carboxylic acids and derivatives

Sub Class

Hexacarboxylic acids and derivatives

Direct Parent

Hexacarboxylic acids and derivatives

Alternative Parents

Substituents

Hexacarboxylic acid or derivatives
Biopterin
Glutamic acid or derivatives
Alpha-amino acid ester
Pterin
Alpha-amino acid or derivatives
Pteridine
Tertiary aliphatic/aromatic amine
Amino fatty acid
Aminopyrimidine
Fatty acid ester
Secondary aliphatic/aromatic amine
Fatty acyl
Pyrimidine
Imidolactam
Heteroaromatic compound
Tertiary amine
Amino acid or derivatives
Amino acid
Carboxylic acid ester
Organoheterocyclic compound
Secondary amine
Azacycle
Carboxylic acid
Enamine
Organic oxygen compound
Hydrocarbon derivative
Primary aliphatic amine
Organonitrogen compound
Carbonyl group
Organooxygen compound
Organic oxide
Organopnictogen compound
Primary amine
Organic nitrogen compound
Amine
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Functional Ontology

Not Available

Physical Properties

State

Expected Solid

Predicted Properties

Property	Value	Source
Water Solubility	0.14 g/L	ALOGPS
logP	-3.5	ALOGPS
logP	-9.9	ChemAxon
logS	-3.7	ALOGPS
pKa (Strongest Acidic)	2.33	ChemAxon
pKa (Strongest Basic)	8.48	ChemAxon
Physiological Charge	1	ChemAxon
Hydrogen Acceptor Count	17	ChemAxon
Hydrogen Donor Count	9	ChemAxon
Polar Surface Area	332.37 Å²	ChemAxon
Rotatable Bond Count	20	ChemAxon
Refractivity	168.91 m³·mol⁻¹	ChemAxon
Polarizability	61.43 Å³	ChemAxon
Number of Rings	2	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

Spectra

Spectrum Type	Description	Splash Key	Deposition Date	View
Predicted GC-MS	Predicted GC-MS Spectrum - GC-MS (TMS_3_19) - 70eV, Positive	Not Available	2022-08-08	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 10V, Positive	splash10-05fr-0000419000-4aece9ee9aeb687f3a1f	2015-09-14	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 20V, Positive	splash10-0zgl-5603933000-11aa5a14e6cacf5eb9b8	2015-09-14	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 40V, Positive	splash10-0pk9-6613920000-ea8b525c3404c241f810	2015-09-14	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 10V, Negative	splash10-024u-0600779000-a67e6d858a1b2e40dd23	2015-09-15	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 20V, Negative	splash10-0204-0902844000-86ab2a5c4ea00fb1ec1d	2015-09-15	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 40V, Negative	splash10-000j-2709100000-5fa0d5508195227cc0f9	2015-09-15	View Spectrum
MS	Mass Spectrum (Electron Ionization)	Not Available	2022-08-06	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 100 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 1000 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 200 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 300 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 400 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 500 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 600 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 700 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 800 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 900 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)		2022-08-20	View Spectrum

Chromatographic Retention Times and Retention Indices

Retention Times

Chromatography Type	Technique	Column	Deposition Date	Retention Time (s)
Liquid Chromatography	HILIC	Waters Acquity UPLC-BEH Amide column (eluted)	2025-10-23	895.9
Liquid Chromatography	HILIC	Accucore 150 Amide HILIC (eluted)	2025-10-23	649.5
Liquid Chromatography	Reversed-phase	Hypersil Gold 1.9 µm C18 (eluted)	2025-10-23	106.2
Liquid Chromatography	Reversed-phase	Agilent Zorbax Eclipse Plus C18 (2.1 mm x 150 mm, 3.5 um) (eluted)	2025-10-23	329.9
Liquid Chromatography	Reversed-phase	XBridge C18 3.5u 2.1x50 mm (eluted)	2025-10-23	371.6
Liquid Chromatography	Reversed-phase	Ascentis Express C18 (eluted)	2025-10-23	216.8
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-23	513.2
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-23	1487.9
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC (eluted)	2025-10-23	751.6
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-23	167.1
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-23	923.7
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-23	181.0
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-23	41.2
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-23	1000.1
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-23	813.0
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (void)	2025-10-23	78.1
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-23	388.9
Liquid Chromatography	Reversed-phase	Kinetex Core-Shell C18 2.6 um, 3.0 x 100 mm, Phenomenex (eluted)	2025-10-23	910.7
Liquid Chromatography	Reversed-phase	Waters Atlantis T3 (2.1 x 150 mm, 5 um) (eluted)	2025-10-23	695.7

Retention Indices

Chromatography Type	Peak Label	SMILES	Stationary Phase	Deposition Date	Retention Index
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_1	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1695.14
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_2	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1523.94
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_3	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2262.32
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_4	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2457.29
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_5	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1347.44
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_6	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	634.615
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_7	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	725.479
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_8	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2264.36
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_9	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	3269.63
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_10	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1301.58
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_11	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1581.85
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_12	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2315.04
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_13	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1388.7
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_14	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2292.61
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_15	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	3225.98
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_16	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	1965.55
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_17	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	1764.54
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_18	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2360.07
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_19	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2260.36
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_20	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1955.4
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_21	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1981.69
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_22	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2001.1
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_23	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	1761.94
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_24	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	1576.84
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_25	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	4073.11
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_26	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	3741.04
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_27	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2744.81
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_28	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2239.51
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_29	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2327.25
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_30	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2180.31
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_31	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	3328.06
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_32	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	712.288
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_33	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	700.873
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_34	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2790.31
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_35	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2093.19
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_36	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2769.2
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_37	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1968.45
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_38	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	3687.98
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_39	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1452.77
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_40	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	1912.4
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_41	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	1336.05
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_42	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	431.544
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_43	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2643.62
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_44	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2121.84
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_45	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	1785.7
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_46	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	1121.58
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_47	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2094.85
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_48	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	929.323
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_49	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1654.35
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_50	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1855.77
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_51	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2011.64
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_52	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2800.66
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_53	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1518.75
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_54	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	3004.1
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_55	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	1929.97
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_56	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2564.61
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_57	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1173.13
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_58	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2104.25
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_59	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2317.84
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_60	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	1689.44
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_61	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	1978.33
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_62	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2241.48
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_63	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	3597.3
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_64	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1167.82
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_65	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2135.8
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_66	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2690.69
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_67	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	3251.98
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_68	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	908.205
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_69	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1420.4
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_70	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2312.41
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_71	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	3276.62
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_72	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	-103.809
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_73	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1973.7
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_74	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	1744.27
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_75	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2409.58
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_76	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	-630.984
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_77	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	1698.77
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_78	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	1001.9
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_79	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	4009.18
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_80	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2956.33
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_81	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1463.63
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_82	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	224.986
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_83	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1927.36
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_84	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2640.43
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_85	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2218.12
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_86	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1504.77
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_87	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1382.74
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_88	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2384.8
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_89	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1621.55
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_90	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2344.4
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_91	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2719.4
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_92	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1845.89
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_93	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2198.88
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_94	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1705.85
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_95	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2181.95
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_96	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2637.36
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_97	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1231.21
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_98	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2884.61
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_99	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	1691.71
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_100	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2487.87
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_101	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	473.959
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_102	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	1613.94
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_103	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2876.03
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_104	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2663.05
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_105	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1784.87
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_106	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2223.8
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_107	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2519.99
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_108	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	1899.94
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_109	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	3343.5
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_110	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	3159.82
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_111	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1528.2
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_112	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	-542.071
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_113	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2078.8
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_114	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2191.13
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_115	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1937.69
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_116	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	3028.15
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_117	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2744.94
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_118	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1526.51
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_119	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2183.18
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_120	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2742.95
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_121	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	733.292
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_122	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1727.53
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_123	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1861.64
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_124	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1385.99
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_125	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	1933.58
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_126	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2381.09
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_127	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2078.09
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_128	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1803.54
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_129	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1922.7
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_130	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2654.13
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_131	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2171.68
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_132	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	273.143
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_133	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2494.52
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_134	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	1237.42
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_135	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2076.95
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_136	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	3261.18
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_137	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	1380.24
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_138	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2812.41
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_139	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	556.563
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_140	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2176.54
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_141	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	1268.45
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_142	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2047.04
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_143	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2433.57
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_144	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	326.473
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_145	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	1387.45
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_146	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	1822.63
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_147	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2514.14
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_148	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2013.64
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_149	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	1918.18
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_150	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard non polar	2025-10-23	2413.1
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_151	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2535.38
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_152	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	1914.57
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_153	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	1817.71
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_154	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard non polar	2025-10-23	2284.93
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_155	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	816.504
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_156	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard non polar	2025-10-23	2601.94
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_1	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1965.39
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_2	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1848.6
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_3	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1334.21
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_4	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1677.91
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_5	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2455.39
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_6	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1269.52
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_7	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	3301.83
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_8	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2567.74
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_9	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1711.88
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_10	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2876.45
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_11	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2255.42
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_12	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2942.42
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_13	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1777.51
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_14	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1009.7
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_15	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2369.82
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_16	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2797.52
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_17	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	595.788
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_18	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1890.25
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_19	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3669.15
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_20	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1143.07
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_21	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	284.842
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_22	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	4157.29
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_23	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2928.76
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_24	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	1634.71
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_25	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2753.62
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_26	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2286.48
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_27	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2697.04
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_28	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3077.47
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_29	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	1607.71
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_30	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	2280.53
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_31	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1967.92
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_32	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2025.65
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_33	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1050.1
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_34	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	1256.65
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_35	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	2927.82
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_36	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2093.22
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_37	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2898.36
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_38	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1256.73
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_39	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1308.64
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_40	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2838.72
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_41	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	1230.48
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_42	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2283.55
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_43	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1920.81
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_44	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	1649.17
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_45	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	2101.63
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_46	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	3639.73
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_47	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2008.7
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_48	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2427.3
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_49	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2587.08
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_50	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2377.54
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_51	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3025.85
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_52	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1947.7
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_53	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2128.51
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_54	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	4298.91
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_55	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	1629.1
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_56	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	244.481
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_57	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2209.41
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_58	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2874.32
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_59	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3234.69
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_60	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2793.1
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_61	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	802.22
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_62	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1448.18
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_63	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1615.09
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_64	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1760.09
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_65	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2443.79
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_66	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2266.71
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_67	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	2490.17
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_68	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	816.018
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_69	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3131.47
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_70	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2994.41
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_71	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	3900.05
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_72	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	1095.53
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_73	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1230.2
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_74	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	1952.35
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_75	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	2721.25
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_76	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3243.98
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_77	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	1575.89
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_78	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	2262.55
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_79	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2187.75
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_80	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3273.45
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_81	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2820.44
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_82	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3527.15
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_83	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	4041.81
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_84	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	3322.89
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_85	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	3076.99
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_86	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3216.24
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_87	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2508.7
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_88	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2539.93
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_89	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1186.39
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_90	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2132.66
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_91	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	1362.57
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_92	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2178.63
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_93	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3720.7
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_94	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1894.02
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_95	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2088.8
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_96	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	1617.56
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_97	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2154.18
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_98	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2545.08
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_99	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	3559.51
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_100	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	4273.59
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_101	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2026.95
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_102	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	2303.0
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_103	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2528.4
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_104	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1669.32
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_105	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2935.43
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_106	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3754.49
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_107	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1497.29
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_108	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2093.79
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_109	CC(OC(=O)[C@H](CCC(=O)O[Si](C)(C)C)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	2841.75
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_110	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2019.35
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_111	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2900.82
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_112	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1987.63
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_113	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2302.31
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_114	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	721.651
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_115	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1275.31
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_116	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	1372.42
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_117	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	2819.78
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_118	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1594.44
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_119	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2777.8
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_120	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	3317.77
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_121	CC(OC(=O)[C@@H](N)CCC(=O)O[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	696.691
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_122	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2650.23
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_123	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2864.82
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_124	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1852.16
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_125	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2608.53
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_126	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	2288.83
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_127	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2166.73
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_128	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	-132.812
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_129	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3987.52
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_130	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	1680.01
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_131	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	2029.39
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_132	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3142.23
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_133	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	1869.79
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_134	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	1315.84
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_135	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3063.25
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_136	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	1616.58
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_137	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	1884.6
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_138	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	1700.88
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_139	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2552.75
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_140	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	2021.48
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_141	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	1094.07
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_142	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2580.54
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_143	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	1464.09
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_144	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	456.782
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_145	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2113.95
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_146	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	2675.7
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_147	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	971.768
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_148	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	1500.66
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_149	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2039.08
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_150	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)[NH]2)N1C	standard polar	2025-10-23	3148.64
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_151	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	2255.97
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_152	CC(OC(=O)[C@H](CCC(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	2548.54
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_153	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	1932.7
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_154	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)[NH]2)N1C	standard polar	2025-10-23	1610.95
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_155	CC(OC(=O)[C@H](CCC(=O)O)N[Si](C)(C)C)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CNC2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	3388.17
Gas Chromatography	5-Methyltetrahydropteroyltri-L-glutamic acid_TMS_156	CC(OC(=O)[C@@H](N)CCC(=O)O)C(OC(=O)[C@@H](N)CCC(=O)O)C1=CN([Si](C)(C)C)C2=C(C(OC(=O)[C@@H](N)CCC(=O)O)=NC(=N[Si](C)(C)C)N2[Si](C)(C)C)N1C	standard polar	2025-10-23	3504.1

Biological Properties

Cellular Locations

Not Available

Biospecimen Locations

Not Available

Tissue Locations

Not Available

Associated OMIM IDs

114500 (Colorectal cancer)
610247 (Eosinophilic esophagitis)

Human Proteins and Enzymes

Protein ID	Protein Name	Protein Type	Uniprot ID	Species

Human Pathways

Pathways

Name	SMPDB/PathBank

Microbial Pathways

Pathways

Not Available

Metabolic Reactions

Reactions

This table shows at most 20 reactions. For the full list of associated reactions:

See All Associated Reactions

Reaction ID	Precursor	Product	Enzyme	Reaction Type	Data Source	Reference

Health Effects and Bioactivity

Health Outcome/Bioactivity	Metabolite Response/Effect	Evidence Type	Host and Biospecimen	Data Source	Reference

Microbial Sources

Superkingdom/Kingdom	Phylum	Total species	Hosts and Body Sites	Microbial Links
Bacteria/Eubacteria	Proteobacteria	1	Human ; Human feces; Human feces; pleural fluid plaque; bal	Unknown
Eukaryota/Fungi	Ascomycota	1	Human feces; Human saliva	Unknown

Exposure Sources

Other Exposures

Source Type	Data Source	Reference

Host Biospecimen and Location

Host and Biospecimen	Status	Mean	Std	Min	Max	Units	Age	Sex	Health Condition	Data Source	Reference

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FooDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

440359

PDB ID

Not Available

ChEBI ID

Not Available

Food Biomarker Ontology

Not Available

CMMC Knowledgebase

Not Available

General References

van der Werf MJ, Overkamp KM, Muilwijk B, Coulier L, Hankemeier T: Microbial metabolomics: toward a platform with full metabolome coverage. Anal Biochem. 2007 Nov 1;370(1):17-25. doi: 10.1016/j.ab.2007.07.022. Epub 2007 Aug 1. [PubMed:17765195 ]
Winder CL, Dunn WB, Schuler S, Broadhurst D, Jarvis R, Stephens GM, Goodacre R: Global metabolic profiling of Escherichia coli cultures: an evaluation of methods for quenching and extraction of intracellular metabolites. Anal Chem. 2008 Apr 15;80(8):2939-48. doi: 10.1021/ac7023409. Epub 2008 Mar 11. [PubMed:18331064 ]
Keseler IM, Collado-Vides J, Santos-Zavaleta A, Peralta-Gil M, Gama-Castro S, Muniz-Rascado L, Bonavides-Martinez C, Paley S, Krummenacker M, Altman T, Kaipa P, Spaulding A, Pacheco J, Latendresse M, Fulcher C, Sarker M, Shearer AG, Mackie A, Paulsen I, Gunsalus RP, Karp PD: EcoCyc: a comprehensive database of Escherichia coli biology. Nucleic Acids Res. 2011 Jan;39(Database issue):D583-90. doi: 10.1093/nar/gkq1143. Epub 2010 Nov 21. [PubMed:21097882 ]
Kanehisa M, Goto S, Sato Y, Furumichi M, Tanabe M: KEGG for integration and interpretation of large-scale molecular data sets. Nucleic Acids Res. 2012 Jan;40(Database issue):D109-14. doi: 10.1093/nar/gkr988. Epub 2011 Nov 10. [PubMed:22080510 ]

Showing metabocard for 5-Methyltetrahydropteroyltri-L-glutamic acid (MMDBc0029547)

MOL for #<Metabolite:0x00007f9ad0172948>

3D MOL for #<Metabolite:0x00007f9ad0172948>

3D SDF for #<Metabolite:0x00007f9ad0172948>

3D-SDF for #<Metabolite:0x00007f9ad0172948>

PDB for #<Metabolite:0x00007f9ad0172948>

3D PDB for #<Metabolite:0x00007f9ad0172948>

SMILES for #<Metabolite:0x00007f9ad0172948>

INCHI for #<Metabolite:0x00007f9ad0172948>

Structure for #<Metabolite:0x00007f9ad0172948>

3D Structure for #<Metabolite:0x00007f9ad0172948>