MiMeDB: Showing metabocard for Globosumone C (MMDBc0013309)

Record Information

Version

2.0

Status

Detected and Quantified

Creation Date

2021-05-15 04:38:26 UTC

Update Date

2025-10-07 16:06:07 UTC

Metabolite ID

MMDBc0013309

Metabolite Identification

Common Name

Globosumone C

Description

Globosumone C is a member of the class of metabolites known as polyketides. There is limited literature available on this compound, indicating that further research is needed to fully understand its properties and potential biological activities.

Structure

MOL SDF PDB SMILES InChI


  Mrv1652305152106382D          

 22 22  0  0  1  0            999 V2000
    9.2881    0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5724   -0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   10.0026   -0.8250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.2881   -2.0625    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.4302   -0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.2881   -0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.2868   -0.8250    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   10.0026   -1.6500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.5737   -1.6500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.7158   -0.8250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.5737   -0.8250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.0013   -0.4125    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    7.8592   -0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.2868   -1.6500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   10.7171   -2.0625    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    7.8592   -2.0625    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.7158   -1.6500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.0013    0.4125    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    7.8592    0.4125    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    7.1447   -0.8250    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.2868    0.0000    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.0013   -1.2375    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
  6  1  1  0  0  0  0
  6  3  2  0  0  0  0
  7  2  1  0  0  0  0
  8  3  1  0  0  0  0
  8  4  2  0  0  0  0
  9  4  1  0  0  0  0
 10  5  1  0  0  0  0
 11  6  1  0  0  0  0
 11  9  2  0  0  0  0
 12  7  1  0  0  0  0
 12 10  1  0  0  0  0
 13 11  1  0  0  0  0
  7 14  1  6  0  0  0
 15  8  1  0  0  0  0
 16  9  1  0  0  0  0
 17 10  2  0  0  0  0
 12 18  1  1  0  0  0
 19 13  2  0  0  0  0
 20  5  1  0  0  0  0
 20 13  1  0  0  0  0
  7 21  1  6  0  0  0
 12 22  1  1  0  0  0
M  END
> <DATABASE_ID>
MMDBc0013309

> <DATABASE_NAME>
MIME

> <SMILES>
[H][C@@](C)(O)[C@]([H])(O)C(=O)COC(=O)C1=C(O)C=C(O)C=C1C

> <INCHI_IDENTIFIER>
InChI=1S/C13H16O7/c1-6-3-8(15)4-9(16)11(6)13(19)20-5-10(17)12(18)7(2)14/h3-4,7,12,14-16,18H,5H2,1-2H3/t7-,12-/m0/s1

> <INCHI_KEY>
QKZBVIRYEJQQDG-MADCSZMMSA-N

> <FORMULA>
C13H16O7

> <MOLECULAR_WEIGHT>
284.264

> <EXACT_MASS>
284.089602855

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
36

> <JCHEM_AVERAGE_POLARIZABILITY>
27.61941369010595

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
4

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
(3S,4S)-3,4-dihydroxy-2-oxopentyl 2,4-dihydroxy-6-methylbenzoate

> <ALOGPS_LOGP>
0.57

> <JCHEM_LOGP>
1.461803611333334

> <ALOGPS_LOGS>
-1.78

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
1

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
10.5481082123015

> <JCHEM_PKA_STRONGEST_ACIDIC>
8.696412174733629

> <JCHEM_PKA_STRONGEST_BASIC>
-3.0881760966898204

> <JCHEM_POLAR_SURFACE_AREA>
124.29000000000002

> <JCHEM_REFRACTIVITY>
68.8806

> <JCHEM_ROTATABLE_BOND_COUNT>
6

> <JCHEM_RULE_OF_FIVE>
1

> <ALOGPS_SOLUBILITY>
4.74e+00 g/l

> <JCHEM_TRADITIONAL_IUPAC>
(3S,4S)-3,4-dihydroxy-2-oxopentyl 2,4-dihydroxy-6-methylbenzoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 15-MAY-21   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   15-MAY-21         0                                  
HETATM    1  C   UNK     0      17.338   0.770   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       6.668  -0.770   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      18.672  -1.540   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      17.338  -3.850   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      12.003  -0.770   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      17.338  -0.770   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       8.002  -1.540   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      18.672  -3.080   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      16.004  -3.080   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      10.669  -1.540   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      16.004  -1.540   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       9.336  -0.770   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      14.670  -0.770   0.000  0.00  0.00           C+0
HETATM   14  O   UNK     0       8.002  -3.080   0.000  0.00  0.00           O+0
HETATM   15  O   UNK     0      20.005  -3.850   0.000  0.00  0.00           O+0
HETATM   16  O   UNK     0      14.670  -3.850   0.000  0.00  0.00           O+0
HETATM   17  O   UNK     0      10.669  -3.080   0.000  0.00  0.00           O+0
HETATM   18  O   UNK     0       9.336   0.770   0.000  0.00  0.00           O+0
HETATM   19  O   UNK     0      14.670   0.770   0.000  0.00  0.00           O+0
HETATM   20  O   UNK     0      13.337  -1.540   0.000  0.00  0.00           O+0
HETATM   21  H   UNK     0       8.002   0.000   0.000  0.00  0.00           H+0
HETATM   22  H   UNK     0       9.336  -2.310   0.000  0.00  0.00           H+0
CONECT    1    6                                                            
CONECT    2    7                                                            
CONECT    3    6    8                                                       
CONECT    4    8    9                                                       
CONECT    5   10   20                                                       
CONECT    6    1    3   11                                                  
CONECT    7    2   12   14   21                                             
CONECT    8    3    4   15                                                  
CONECT    9    4   11   16                                                  
CONECT   10    5   12   17                                                  
CONECT   11    6    9   13                                                  
CONECT   12    7   10   18   22                                             
CONECT   13   11   19   20                                                  
CONECT   14    7                                                            
CONECT   15    8                                                            
CONECT   16    9                                                            
CONECT   17   10                                                            
CONECT   18   12                                                            
CONECT   19   13                                                            
CONECT   20    5   13                                                       
CONECT   21    7                                                            
CONECT   22   12                                                            
MASTER        0    0    0    0    0    0    0    0   22    0   44    0
END

Synonyms

Value	Source
2'-oxo-3'r,4's-Dihydroxypentyl orsellinate	ChEBI
2'-oxo-3'r,4's-Dihydroxypentyl orsellinic acid	Generator

Molecular Formula

C₁₃H₁₆O₇

Average Mass

284.264

Monoisotopic Mass

284.089602855

IUPAC Name

(3S,4S)-3,4-dihydroxy-2-oxopentyl 2,4-dihydroxy-6-methylbenzoate

Traditional Name

(3S,4S)-3,4-dihydroxy-2-oxopentyl 2,4-dihydroxy-6-methylbenzoate

CAS Registry Number

Not Available

SMILES

[H][C@@](C)(O)[C@]([H])(O)C(=O)COC(=O)C1=C(O)C=C(O)C=C1C

InChI Identifier

InChI=1S/C13H16O7/c1-6-3-8(15)4-9(16)11(6)13(19)20-5-10(17)12(18)7(2)14/h3-4,7,12,14-16,18H,5H2,1-2H3/t7-,12-/m0/s1

InChI Key

QKZBVIRYEJQQDG-MADCSZMMSA-N

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as p-hydroxybenzoic acid alkyl esters. These are aromatic compounds containing a benzoic acid, which is esterified with an alkyl group and para-substituted with a hydroxyl group.

Kingdom

Organic compounds

Super Class

Benzenoids

Class

Benzene and substituted derivatives

Sub Class

Benzoic acids and derivatives

Direct Parent

p-Hydroxybenzoic acid alkyl esters

Alternative Parents

Substituents

P-hydroxybenzoic acid alkyl ester
O-hydroxybenzoic acid ester
Dihydroxybenzoic acid
Salicylic acid or derivatives
Benzoyl
M-cresol
Resorcinol
1-hydroxy-4-unsubstituted benzenoid
1-hydroxy-2-unsubstituted benzenoid
Toluene
Phenol
Acyloin
Beta-hydroxy ketone
Monosaccharide
Alpha-hydroxy ketone
Vinylogous acid
Secondary alcohol
Ketone
Carboxylic acid ester
1,2-diol
Carboxylic acid derivative
Monocarboxylic acid or derivatives
Organic oxygen compound
Carbonyl group
Hydrocarbon derivative
Organic oxide
Alcohol
Organooxygen compound
Aromatic homomonocyclic compound

Molecular Framework

Aromatic homomonocyclic compounds

External Descriptors

resorcinols (CHEBI:68707 )
benzoate ester (CHEBI:68707 )

Functional Ontology

Not Available

Physical Properties

State

Expected Solid

Predicted Properties

Property	Value	Source
Water Solubility	4.74 g/L	ALOGPS
logP	0.57	ALOGPS
logP	1.46	ChemAxon
logS	-1.8	ALOGPS
pKa (Strongest Acidic)	8.7	ChemAxon
pKa (Strongest Basic)	-3.1	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	4	ChemAxon
Polar Surface Area	124.29 Å²	ChemAxon
Rotatable Bond Count	6	ChemAxon
Refractivity	68.88 m³·mol⁻¹	ChemAxon
Polarizability	27.62 Å³	ChemAxon
Number of Rings	1	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	Yes	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

Spectra

Spectrum Type	Description	Splash Key	Deposition Date	View
Predicted GC-MS	Predicted GC-MS Spectrum - GC-MS (TMS_2_2) - 70eV, Positive	Not Available	2022-08-08	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 10V, Positive	Not Available	2022-08-09	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 20V, Positive	Not Available	2022-08-09	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 40V, Positive	Not Available	2022-08-09	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 10V, Negative	Not Available	2022-08-09	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 20V, Negative	Not Available	2022-08-09	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 40V, Negative	Not Available	2022-08-09	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 100 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 1000 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 200 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 300 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 400 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 500 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 600 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 700 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 800 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 900 MHz, H₂O, predicted)		2022-08-21	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)		2022-08-21	View Spectrum

Chromatographic Retention Times and Retention Indices

Retention Times

Chromatography Type	Technique	Column	Deposition Date	Retention Time (s)
Liquid Chromatography	HILIC	Waters Acquity UPLC-BEH Amide column (eluted)	2025-10-23	112.2
Liquid Chromatography	HILIC	Accucore 150 Amide HILIC (void)	2025-10-23	65.7
Liquid Chromatography	Reversed-phase	Hypersil Gold 1.9 µm C18 (eluted)	2025-10-23	308.1
Liquid Chromatography	Reversed-phase	Agilent Zorbax Eclipse Plus C18 (2.1 mm x 150 mm, 3.5 um) (eluted)	2025-10-23	419.5
Liquid Chromatography	Reversed-phase	XBridge C18 3.5u 2.1x50 mm (eluted)	2025-10-23	436.2
Liquid Chromatography	Reversed-phase	Ascentis Express C18 (eluted)	2025-10-23	212.9
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-23	1573.7
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (void)	2025-10-23	110.2
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC (eluted)	2025-10-23	451.7
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-23	184.9
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-23	127.9
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-23	143.1
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-23	94.2
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-23	250.3
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-23	393.0
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-23	71.5
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-23	301.0
Liquid Chromatography	Reversed-phase	Kinetex Core-Shell C18 2.6 um, 3.0 x 100 mm, Phenomenex (eluted)	2025-10-23	1320.9
Liquid Chromatography	Reversed-phase	Waters Atlantis T3 (2.1 x 150 mm, 5 um) (eluted)	2025-10-23	673.5

Retention Indices

Chromatography Type	Peak Label	SMILES	Stationary Phase	Deposition Date	Retention Index
Gas Chromatography	Globosumone C_TMS_1	CC1=CC(O)=CC(O)=C1C(=O)OCC(=O)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2319.77
Gas Chromatography	Globosumone C_TMS_2	CC1=CC(O)=CC(O)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard non polar	2025-10-23	2049.49
Gas Chromatography	Globosumone C_TMS_3	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O)[C@H](C)O	standard non polar	2025-10-23	1072.58
Gas Chromatography	Globosumone C_TMS_4	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(=O)[C@@H](O)[C@H](C)O	standard non polar	2025-10-23	1799.52
Gas Chromatography	Globosumone C_TMS_5	CC1=CC(O)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O	standard non polar	2025-10-23	2002.07
Gas Chromatography	Globosumone C_TMS_6	CC1=CC(O)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O	standard non polar	2025-10-23	2606.96
Gas Chromatography	Globosumone C_TMS_7	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(=O)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	1849.17
Gas Chromatography	Globosumone C_TMS_8	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2261.71
Gas Chromatography	Globosumone C_TMS_9	CC1=CC(O)=CC(O)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2587.39
Gas Chromatography	Globosumone C_TMS_10	CC1=CC(O)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2162.6
Gas Chromatography	Globosumone C_TMS_11	CC1=CC(O)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	1783.16
Gas Chromatography	Globosumone C_TMS_12	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard non polar	2025-10-23	1722.1
Gas Chromatography	Globosumone C_TMS_13	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard non polar	2025-10-23	2317.52
Gas Chromatography	Globosumone C_TMS_14	CC1=CC(O)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O	standard non polar	2025-10-23	2077.02
Gas Chromatography	Globosumone C_TMS_15	CC1=CC(O)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard non polar	2025-10-23	1580.94
Gas Chromatography	Globosumone C_TMS_16	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O)[C@H](C)O	standard non polar	2025-10-23	1677.39
Gas Chromatography	Globosumone C_TMS_17	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O	standard non polar	2025-10-23	1929.53
Gas Chromatography	Globosumone C_TMS_18	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O	standard non polar	2025-10-23	2544.12
Gas Chromatography	Globosumone C_TMS_19	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O	standard non polar	2025-10-23	2094.41
Gas Chromatography	Globosumone C_TMS_20	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O	standard non polar	2025-10-23	1450.87
Gas Chromatography	Globosumone C_TMS_21	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	1990.27
Gas Chromatography	Globosumone C_TMS_22	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	1984.77
Gas Chromatography	Globosumone C_TMS_23	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2042.64
Gas Chromatography	Globosumone C_TMS_24	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2508.68
Gas Chromatography	Globosumone C_TMS_25	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2261.7
Gas Chromatography	Globosumone C_TMS_26	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2302.7
Gas Chromatography	Globosumone C_TMS_27	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2000.8
Gas Chromatography	Globosumone C_TMS_28	CC1=CC(O)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2481.82
Gas Chromatography	Globosumone C_TMS_29	CC1=CC(O)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2361.41
Gas Chromatography	Globosumone C_TMS_30	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard non polar	2025-10-23	1739.27
Gas Chromatography	Globosumone C_TMS_31	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O	standard non polar	2025-10-23	2497.55
Gas Chromatography	Globosumone C_TMS_32	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard non polar	2025-10-23	1654.02
Gas Chromatography	Globosumone C_TMS_33	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O	standard non polar	2025-10-23	1360.2
Gas Chromatography	Globosumone C_TMS_34	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard non polar	2025-10-23	1464.44
Gas Chromatography	Globosumone C_TMS_35	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O	standard non polar	2025-10-23	3119.74
Gas Chromatography	Globosumone C_TMS_36	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O	standard non polar	2025-10-23	2300.7
Gas Chromatography	Globosumone C_TMS_37	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	1746.52
Gas Chromatography	Globosumone C_TMS_38	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	980.723
Gas Chromatography	Globosumone C_TMS_39	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2311.63
Gas Chromatography	Globosumone C_TMS_40	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2053.2
Gas Chromatography	Globosumone C_TMS_41	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2099.6
Gas Chromatography	Globosumone C_TMS_42	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	1036.89
Gas Chromatography	Globosumone C_TMS_43	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2161.25
Gas Chromatography	Globosumone C_TMS_44	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O	standard non polar	2025-10-23	1587.7
Gas Chromatography	Globosumone C_TMS_45	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard non polar	2025-10-23	2460.68
Gas Chromatography	Globosumone C_TMS_46	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2031.53
Gas Chromatography	Globosumone C_TMS_47	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard non polar	2025-10-23	2264.21
Gas Chromatography	Globosumone C_TMS_1	CC1=CC(O)=CC(O)=C1C(=O)OCC(=O)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	1809.9
Gas Chromatography	Globosumone C_TMS_2	CC1=CC(O)=CC(O)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard polar	2025-10-23	2425.48
Gas Chromatography	Globosumone C_TMS_3	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O)[C@H](C)O	standard polar	2025-10-23	1902.07
Gas Chromatography	Globosumone C_TMS_4	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(=O)[C@@H](O)[C@H](C)O	standard polar	2025-10-23	2421.62
Gas Chromatography	Globosumone C_TMS_5	CC1=CC(O)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O	standard polar	2025-10-23	2961.73
Gas Chromatography	Globosumone C_TMS_6	CC1=CC(O)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O	standard polar	2025-10-23	2069.32
Gas Chromatography	Globosumone C_TMS_7	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(=O)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	2290.73
Gas Chromatography	Globosumone C_TMS_8	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	1533.06
Gas Chromatography	Globosumone C_TMS_9	CC1=CC(O)=CC(O)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	2454.44
Gas Chromatography	Globosumone C_TMS_10	CC1=CC(O)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	2280.02
Gas Chromatography	Globosumone C_TMS_11	CC1=CC(O)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	1518.19
Gas Chromatography	Globosumone C_TMS_12	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard polar	2025-10-23	920.485
Gas Chromatography	Globosumone C_TMS_13	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard polar	2025-10-23	2205.19
Gas Chromatography	Globosumone C_TMS_14	CC1=CC(O)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O	standard polar	2025-10-23	1270.39
Gas Chromatography	Globosumone C_TMS_15	CC1=CC(O)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard polar	2025-10-23	2304.79
Gas Chromatography	Globosumone C_TMS_16	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O)[C@H](C)O	standard polar	2025-10-23	2036.14
Gas Chromatography	Globosumone C_TMS_17	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O	standard polar	2025-10-23	2224.34
Gas Chromatography	Globosumone C_TMS_18	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O	standard polar	2025-10-23	2700.27
Gas Chromatography	Globosumone C_TMS_19	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O	standard polar	2025-10-23	2425.69
Gas Chromatography	Globosumone C_TMS_20	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O	standard polar	2025-10-23	1374.29
Gas Chromatography	Globosumone C_TMS_21	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	1512.1
Gas Chromatography	Globosumone C_TMS_22	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	2813.81
Gas Chromatography	Globosumone C_TMS_23	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	1432.04
Gas Chromatography	Globosumone C_TMS_24	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	2736.26
Gas Chromatography	Globosumone C_TMS_25	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	2153.16
Gas Chromatography	Globosumone C_TMS_26	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	1911.43
Gas Chromatography	Globosumone C_TMS_27	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	1749.05
Gas Chromatography	Globosumone C_TMS_28	CC1=CC(O)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	2179.04
Gas Chromatography	Globosumone C_TMS_29	CC1=CC(O)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	1723.38
Gas Chromatography	Globosumone C_TMS_30	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard polar	2025-10-23	2581.93
Gas Chromatography	Globosumone C_TMS_31	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O	standard polar	2025-10-23	1785.86
Gas Chromatography	Globosumone C_TMS_32	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard polar	2025-10-23	1772.46
Gas Chromatography	Globosumone C_TMS_33	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O	standard polar	2025-10-23	1923.83
Gas Chromatography	Globosumone C_TMS_34	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard polar	2025-10-23	3405.79
Gas Chromatography	Globosumone C_TMS_35	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O	standard polar	2025-10-23	1674.54
Gas Chromatography	Globosumone C_TMS_36	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O	standard polar	2025-10-23	2696.33
Gas Chromatography	Globosumone C_TMS_37	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(=O)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	2098.32
Gas Chromatography	Globosumone C_TMS_38	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	2109.83
Gas Chromatography	Globosumone C_TMS_39	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	1998.51
Gas Chromatography	Globosumone C_TMS_40	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	1738.82
Gas Chromatography	Globosumone C_TMS_41	CC1=CC(O[Si](C)(C)C)=CC(O)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	2781.4
Gas Chromatography	Globosumone C_TMS_42	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	1420.92
Gas Chromatography	Globosumone C_TMS_43	CC1=CC(O)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	2248.65
Gas Chromatography	Globosumone C_TMS_44	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O	standard polar	2025-10-23	1336.17
Gas Chromatography	Globosumone C_TMS_45	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O	standard polar	2025-10-23	2603.04
Gas Chromatography	Globosumone C_TMS_46	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OCC(O[Si](C)(C)C)=C(O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	2509.41
Gas Chromatography	Globosumone C_TMS_47	CC1=CC(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1C(=O)OC=C(O[Si](C)(C)C)[C@@H](O[Si](C)(C)C)[C@H](C)O[Si](C)(C)C	standard polar	2025-10-23	1759.06

Biological Properties

Cellular Locations

Not Available

Biospecimen Locations

Not Available

Tissue Locations

Not Available

Associated OMIM IDs

114500 (Colorectal cancer)
610247 (Eosinophilic esophagitis)

Human Proteins and Enzymes

Protein ID	Protein Name	Protein Type	Uniprot ID	Species

Human Pathways

Pathways

Name	SMPDB/PathBank

Microbial Pathways

Pathways

Not Available

Metabolic Reactions

Reactions

This table shows at most 20 reactions. For the full list of associated reactions:

See All Associated Reactions

Reaction ID	Precursor	Product	Enzyme	Reaction Type	Data Source	Reference

Health Effects and Bioactivity

Health Outcome/Bioactivity	Metabolite Response/Effect	Evidence Type	Host and Biospecimen	Data Source	Reference

Microbial Sources

Superkingdom/Kingdom	Phylum	Total species	Hosts and Body Sites	Microbial Links
Eukaryota/Fungi	Ascomycota	1	Human feces	Metabolic reconstruction

Exposure Sources

Other Exposures

Source Type	Data Source	Reference

Host Biospecimen and Location

Host and Biospecimen	Status	Mean	Std	Min	Max	Units	Age	Sex	Health Condition	Data Source	Reference

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FooDB ID

Not Available

KNApSAcK ID

C00042562

Chemspider ID

24714045

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

44583956

PDB ID

Not Available

ChEBI ID

68707

Food Biomarker Ontology

Not Available

CMMC Knowledgebase

Not Available

General References

van Santen JA, Poynton EF, Iskakova D, McMann E, Alsup TA, Clark TN, Fergusson CH, Fewer DP, Hughes AH, McCadden CA, Parra J, Soldatou S, Rudolf JD, Janssen EM, Duncan KR, Linington RG: The Natural Products Atlas 2.0: a database of microbially-derived natural products. Nucleic Acids Res. 2022 Jan 7;50(D1):D1317-D1323. doi: 10.1093/nar/gkab941. [PubMed:34718710 ]

Showing metabocard for Globosumone C (MMDBc0013309)

MOL for #<Metabolite:0x00007fc9459c8748>

3D MOL for #<Metabolite:0x00007fc9459c8748>

3D SDF for #<Metabolite:0x00007fc9459c8748>

3D-SDF for #<Metabolite:0x00007fc9459c8748>

PDB for #<Metabolite:0x00007fc9459c8748>

3D PDB for #<Metabolite:0x00007fc9459c8748>

SMILES for #<Metabolite:0x00007fc9459c8748>

INCHI for #<Metabolite:0x00007fc9459c8748>

Structure for #<Metabolite:0x00007fc9459c8748>

3D Structure for #<Metabolite:0x00007fc9459c8748>